| Title: |
Palladium/N-Heterocyclic Carbene Catalyzed Regio- and Diastereoselective Reaction of Ketones with Allyl Reagents via Inner-Sphere Mechanism. |
| Authors: |
Xue-Long Hou; Da-Chang Bai; Feile Yu; Wan-Ying Wang; Di Chen; Hao Li; Qing-Rong Liu; Chang-Hua Ding; Bo Chen |
| Source: |
Synlett; 2016, Vol. 27 Issue 16, pA151-A155, 5p |
| Subject Terms: |
Palladium; Ketones; Allyl compounds; Density functional theory; Nucleophiles |
| Abstract: |
The article discusses a study related to palladium and N-heterocyclic carbene catalyzed reactions of ketones with allyl reagents. It mentions mechanistic investigations through experiments by using optically active deuterium-labeled allyl reagents and cis-disubstituted cyclohexene along with the Density functional theory (DFT) calculations. It also highlights results showing hard nucleophiles with allyl reagents. |
| Database: |
Complementary Index |