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Impact of erbium doping on critical current density and constituent phase in BSCCO superconductors.

Title: Impact of erbium doping on critical current density and constituent phase in BSCCO superconductors.
Authors: Açikel, S.; Cumhur, İ.; Öztürk, A.; Başoğlu, M.; Düzgün, İ.
Source: Canadian Journal of Physics; 2025, Vol. 103 Issue 10, p1012-1026, 15p
Subject Terms: Critical current density (Superconductivity); High temperature superconductors; Structural failures; Superconductivity; Semiconductors; X-ray diffraction; Doping agents (Chemistry); Ionic structure
Abstract: This work systematically examines the influence of partial substitution of calcium (Ca) by erbium (Er) on the structural integrity and superconducting performance of Bi2Sr2Ca2Cu3O10+δ (BSCCO) high-temperature superconductors. Samples were synthesized through the conventional solid-state reaction method and characterized via X-ray diffraction, scanning electron microscopy, resistivity, and magnetization measurements. Despite the close effective ionic radii of Er and Ca, experimental results revealed that increasing Er content led to a deterioration of the superconducting phase and the emergence of semiconducting characteristics. Quantitative analyses demonstrated a notable reduction in critical current density (Jc), with undoped BSCCO samples exhibiting approximately 14% higher Jc values under equivalent conditions. These findings suggest that while ionic size considerations may permit Er substitution from a stoichiometric perspective, the structural and superconducting phase stability of the BSCCO matrix is adversely affected by Er incorporation. [ABSTRACT FROM AUTHOR]
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Database: Complementary Index