Self-assembly of M4L4 tetrahedral cages incorporating pendant P[double bond, length as m-dash]S and P[double bond, length as m-dash]Se functionalised ligands.
| Title: | Self-assembly of M4L4 tetrahedral cages incorporating pendant P[double bond, length as m-dash]S and P[double bond, length as m-dash]Se functionalised ligands. |
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| Authors: | Butler PWV; Research School of Chemistry, Australian National University, Acton, Canberra, ACT, Australia.; Kruger PE; Ward JS |
| Source: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Aug 22; Vol. 55 (69), pp. 10304-10307. |
| Publication Type: | Journal Article |
| Language: | English |
| Journal Info: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9610838 Publication Model: Print Cited Medium: Internet ISSN: 1364-548X (Electronic) Linking ISSN: 13597345 NLM ISO Abbreviation: Chem Commun (Camb) Subsets: MEDLINE; PubMed not MEDLINE |
| Imprint Name(s): | Original Publication: Cambridge : Royal Society of Chemistry |
| Abstract: | Herein, the synthesis of metal-organic tetrahedral cages featuring flexible thio- and selenophosphate-based ligands is described. The cages were prepared by sub-component self-assembly of A[double bond, length as m-dash]P(OC6H4NH2-4)3 (A = S, Se) or S[double bond, length as m-dash]P(SC6H4NH2-4)3, 2-pyridinecarboxaldehyde, and either Fe[BF4]2 or Co[BF4]2. Preliminary host-guest studies into the ability of the pendant P[double bond, length as m-dash]S and P[double bond, length as m-dash]Se groups to interact with suitable substrates will be discussed. |
| Entry Date(s): | Date Created: 20190810 Latest Revision: 20190822 |
| Update Code: | 20260130 |
| DOI: | 10.1039/c9cc05443j |
| PMID: | 31397447 |
| Database: | MEDLINE |
Journal Article