Water Structure and Properties at Hydrophilic and Hydrophobic Surfaces.
| Title: | Water Structure and Properties at Hydrophilic and Hydrophobic Surfaces. |
|---|---|
| Authors: | Monroe J; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Barry M; Department of Materials, University of California, Santa Barbara, California 93106, USA.; DeStefano A; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Aydogan Gokturk P; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.; Jiao S; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Robinson-Brown D; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Webber T; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Crumlin EJ; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.; Han S; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu.; Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA.; Shell MS; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA; email: shell@engineering.ucsb.edu. |
| Source: | Annual review of chemical and biomolecular engineering [Annu Rev Chem Biomol Eng] 2020 Jun 07; Vol. 11, pp. 523-557. Date of Electronic Publication: 2020 Mar 13. |
| Publication Type: | Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; Review |
| Language: | English |
| Journal Info: | Publisher: Annual Reviews Country of Publication: United States NLM ID: 101574034 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1947-5446 (Electronic) Linking ISSN: 19475438 NLM ISO Abbreviation: Annu Rev Chem Biomol Eng Subsets: MEDLINE |
| Imprint Name(s): | Original Publication: Palo Alto, Calif. : Annual Reviews |
| MeSH Terms: | Water/*chemistry; Solvents/chemistry ; Hydrogen Bonding ; Hydrophobic and Hydrophilic Interactions ; Magnetic Resonance Spectroscopy ; Spectrophotometry ; Surface Properties ; Thermodynamics |
| Abstract: | The properties of water on both molecular and macroscopic surfaces critically influence a wide range of physical behaviors, with applications spanning from membrane science to catalysis to protein engineering. Yet, our current understanding of water interfacing molecular and material surfaces is incomplete, in part because measurement of water structure and molecular-scale properties challenges even the most advanced experimental characterization techniques and computational approaches. This review highlights progress in the ongoing development of tools working to answer fundamental questions on the principles that govern the interactions between water and surfaces. One outstanding and critical question is what universal molecular signatures capture the hydrophobicity of different surfaces in an operationally meaningful way, since traditional macroscopic hydrophobicity measures like contact angles fail to capture even basic properties of molecular or extended surfaces with any heterogeneity at the nanometer length scale. Resolving this grand challenge will require close interactions between state-of-the-art experiments, simulations, and theory, spanning research groups and using agreed-upon model systems, to synthesize an integrated knowledge of solvation water structure, dynamics, and thermodynamics. |
| Contributed Indexing: | Keywords: hydration; hydropathy; hydrophobicity; interfaces; solvation; water |
| Substance Nomenclature: | 0 (Solvents); 059QF0KO0R (Water) |
| Entry Date(s): | Date Created: 20200315 Date Completed: 20210420 Latest Revision: 20210420 |
| Update Code: | 20260130 |
| DOI: | 10.1146/annurev-chembioeng-120919-114657 |
| PMID: | 32169001 |
| Database: | MEDLINE |
Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; Review