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Impact of Thickness-Dependent Nanophotonic Effects on the Optical Response of Color Centers in Hexagonal Boron Nitride.

Title: Impact of Thickness-Dependent Nanophotonic Effects on the Optical Response of Color Centers in Hexagonal Boron Nitride.
Authors: Clua-Provost T; Laboratoire Charles Coulomb, Université de Montpellier and CNRS, 34095 Montpellier, France.; Durand A; Laboratoire Charles Coulomb, Université de Montpellier and CNRS, 34095 Montpellier, France.; Fraunié J; Université de Toulouse, INSA-CNRS-UPS, LPCNO, 135 Avenue Rangueil, 31077 Toulouse, France.; Robert C; Université de Toulouse, INSA-CNRS-UPS, LPCNO, 135 Avenue Rangueil, 31077 Toulouse, France.; Marie X; Université de Toulouse, INSA-CNRS-UPS, LPCNO, 135 Avenue Rangueil, 31077 Toulouse, France.; Li J; Tim Taylor Department of Chemical Engineering, Kansas State University, Manhattan, Kansas 66506, United States.; Edgar JH; Tim Taylor Department of Chemical Engineering, Kansas State University, Manhattan, Kansas 66506, United States.; Gil B; Laboratoire Charles Coulomb, Université de Montpellier and CNRS, 34095 Montpellier, France.; Gérard JM; Université Grenoble Alpes, CEA, Grenoble INP, IRIG, PHELIQS, 38000 Grenoble, France.; Cassabois G; Laboratoire Charles Coulomb, Université de Montpellier and CNRS, 34095 Montpellier, France.; Institut Universitaire de France, 75231 Paris, France.; Jacques V; Laboratoire Charles Coulomb, Université de Montpellier and CNRS, 34095 Montpellier, France.
Source: Nano letters [Nano Lett] 2024 Oct 01. Date of Electronic Publication: 2024 Oct 01.
Publication Model: Ahead of Print
Publication Type: Journal Article
Language: English
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 101088070 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1530-6992 (Electronic) Linking ISSN: 15306984 NLM ISO Abbreviation: Nano Lett Subsets: MEDLINE
Imprint Name(s): Original Publication: Washington, DC : American Chemical Society, c2001-
Abstract: Among a broad diversity of color centers hosted in layered van der Waals materials, the negatively charged boron vacancy (VB-) center in hexagonal boron nitride (hBN) is garnering considerable attention for the development of quantum sensing units on a two-dimensional platform. In this work, we investigate how the optical response of an ensemble of VB- centers evolves with the hBN thickness in a range of a few to hundreds of nanometers. We show that the photoluminescence intensity features a nontrivial evolution with thickness, which is quantitatively reproduced by numerical calculations taking into account thickness-dependent variations of the absorption, radiative lifetime, and radiation pattern of VB- centers. Besides providing an important resource to optimize the performances of quantum sensing units based on VB- centers in hBN, the thickness-dependent nanophotonic effects discussed in this work generally apply to any type of color center embedded in a van der Waals material.
Contributed Indexing: Keywords: 2D materials; color centers; nanophotonic effects; quantum sensing
Entry Date(s): Date Created: 20241001 Latest Revision: 20241001
Update Code: 20260130
DOI: 10.1021/acs.nanolett.4c03300
PMID: 39353565
Database: MEDLINE

Journal Article