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Synergistic anti-friction performance and lubricating film mechanism of erucamide and N-phenyl-α-naphthylamine in polyurea grease at elevated temperatures.

Title: Synergistic anti-friction performance and lubricating film mechanism of erucamide and N-phenyl-α-naphthylamine in polyurea grease at elevated temperatures.
Authors: Liu Q; School of Intelligent Manufacturing, Jianghan University Wuhan 430056 China feedback-ssm@jhun.edu.cn.; Yu W; School of Intelligent Manufacturing, Jianghan University Wuhan 430056 China feedback-ssm@jhun.edu.cn.; Mo Y; School of Mechanical and Electrical Engineering, Wuhan University of Technology Wuhan 430070 China.; Wang J; SAIC-GM-Wuling Automobile Corporation Liuzhou 454007 China.; Liu C; SAIC-GM-Wuling Automobile Corporation Liuzhou 454007 China.; Hong Y; School of Intelligent Manufacturing, Jianghan University Wuhan 430056 China feedback-ssm@jhun.edu.cn.; Zhang Q; School of Intelligent Manufacturing, Jianghan University Wuhan 430056 China feedback-ssm@jhun.edu.cn.; Chen F; State Key Laboratory of Precision Blasting, Jianghan University Wuhan 430056 China.
Source: RSC advances [RSC Adv] 2025 Dec 16; Vol. 15 (58), pp. 50408-50418. Date of Electronic Publication: 2025 Dec 16 (Print Publication: 2025).
Publication Type: Journal Article
Language: English
Journal Info: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101581657 Publication Model: eCollection Cited Medium: Internet ISSN: 2046-2069 (Electronic) Linking ISSN: 20462069 NLM ISO Abbreviation: RSC Adv Subsets: PubMed not MEDLINE
Imprint Name(s): Original Publication: Cambridge [England] : Royal Society of Chemistry, [2011]-
Abstract: The synergistic effect of anti-wear and antioxidant additives in lubricating grease can effectively reduce friction and wear. In this study, a polyurea grease containing 2 wt% erucamide (ER) and 1 wt% N-phenyl-α-naphthylamine (N-PAN) was prepared, and its tribological performance on GCr15 steel at different temperatures was systematically investigated. The results show that the average friction coefficient of the grease with ER and N-PAN decreases by approximately 32% compared with the base polyurea grease, exhibiting the best tribological performance at 75 °C (average friction coefficient = 0.088). Surface characterization reveals that the synergistic action of ER and N-PAN promotes the formation of a dense and durable lubricating film. ER molecules form a bilayer structure, filling the voids of the base oil and transforming sliding friction into rolling friction, while N-PAN effectively inhibits oxidation and retards film degradation. This synergistic mechanism significantly enhances the high-temperature friction-reducing and antioxidative properties of the grease, demonstrating its potential for high-temperature mechanical lubrication applications.; (This journal is © The Royal Society of Chemistry.)
Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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Entry Date(s): Date Created: 20251218 Date Completed: 20251218 Latest Revision: 20251220
Update Code: 20260130
PubMed Central ID: PMC12706631
DOI: 10.1039/d5ra06889d
PMID: 41409730
Database: MEDLINE

Journal Article