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Structural and Rheological Principles of Formation of Stable Bituminous Sealants with Polymer-Fiber Reinforcement

Title: Structural and Rheological Principles of Formation of Stable Bituminous Sealants with Polymer-Fiber Reinforcement
Authors: Gulbarshin K. Shambilova; Saule Bukanova; Zhanar Kadasheva; Nagima Karabassova; Mikhail S. Kuzin; Igor V. Gumennyi; Ivan Yu. Skvortsov; Igor S. Makarov
Source: Infrastructures ; Volume 11 ; Issue 3 ; Pages: 104
Publisher Information: Multidisciplinary Digital Publishing Institute
Publication Year: 2026
Collection: MDPI Open Access Publishing
Subject Terms: polymer modified bitumen; rheology; cellulose fiber; FTIR spectra; composites; adhesion
Description: The development of durable road sealing materials capable of maintaining performance under combined mechanical and climatic loads remains a critical challenge for modern infrastructure. Conventional bitumen-based sealants exhibit limited resistance to high-temperature deformation, cracking, and adhesion degradation, leading to reduced service life. This study proposes a rheology-oriented approach to the design of polymer-reinforced bituminous sealants based on penetration-grade bitumen 50/70 and 70/100 modified with styrene–butadiene–styrene (SBS) copolymers up to 9 wt.% and reinforced with cellulose fibers. The rheological behavior of the developed composites was investigated using dynamic shear rheometry to determine the complex shear modulus (G*), phase angle (δ), and temperature–frequency dependencies in the range from −20 to +90 °C, while infrared spectroscopy was employed to assess intermolecular interactions. Adhesion performance was evaluated at different temperature. The modified systems demonstrated a 5–10-fold increase in G*/sinδ enhanced high-temperature stability, and improved adhesion and crack resistance compared to base bitumen. Based on the obtained rheological and performance indicators, the developed composition was approved for subsequent pilot-scale testing and field validation as a promising road sealing material.
Document Type: text
File Description: application/pdf
Language: English
Relation: https://dx.doi.org/10.3390/infrastructures11030104
DOI: 10.3390/infrastructures11030104
Availability: https://doi.org/10.3390/infrastructures11030104
Rights: https://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.1528F229
Database: BASE