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The river as a chemostat: fresh perspectives on dissolved organic matter flowing down the river continuum

Title: The river as a chemostat: fresh perspectives on dissolved organic matter flowing down the river continuum
Authors: Creed, Irena F.; McKnight, Diane M.; Pellerin, Brian A.; Green, Mark B.; Bergamaschi, Brian A.; Aiken, George R.; Burns, Douglas A.; Findlay, Stuart E.G.; Shanley, Jamie B.; Striegl, Rob G.; Aulenbach, Brent T.; Clow, David W.; Laudon, Hjalmar; McGlynn, Brian L.; McGuire, Kevin J.; Smith, Richard A.; Stackpoole, Sarah M.
Contributors: Smith, Ralph
Source: Canadian Journal of Fisheries and Aquatic Sciences ; volume 72, issue 8, page 1272-1285 ; ISSN 0706-652X 1205-7533
Publisher Information: Canadian Science Publishing
Publication Year: 2015
Description: A better understanding is needed of how hydrological and biogeochemical processes control dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) composition from headwaters downstream to large rivers. We examined a large DOM dataset from the National Water Information System of the US Geological Survey, which represents approximately 100 000 measurements of DOC concentration and DOM composition at many sites along rivers across the United States. Application of quantile regression revealed a tendency towards downstream spatial and temporal homogenization of DOC concentrations and a shift from dominance of aromatic DOM in headwaters to more aliphatic DOM downstream. The DOC concentration–discharge (C-Q) relationships at each site revealed a downstream tendency towards a slope of zero. We propose that despite complexities in river networks that have driven many revisions to the River Continuum Concept, rivers show a tendency towards chemostasis (C-Q slope of zero) because of a downstream shift from a dominance of hydrologic drivers that connect terrestrial DOM sources to streams in the headwaters towards a dominance of instream and near-stream biogeochemical processes that result in preferential losses of aromatic DOM and preferential gains of aliphatic DOM.
Document Type: article in journal/newspaper
Language: English
DOI: 10.1139/cjfas-2014-0400
Availability: https://doi.org/10.1139/cjfas-2014-0400; https://cdnsciencepub.com/doi/full-xml/10.1139/cjfas-2014-0400; https://cdnsciencepub.com/doi/pdf/10.1139/cjfas-2014-0400
Rights: http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining
Accession Number: edsbas.17A1AC35
Database: BASE