ChemInform Abstract: Enantioselective Iodine(III)‐Mediated Synthesis of α‐Tosyloxy Ketones: Breaking the Selectivity Barrier.
| Title: | ChemInform Abstract: Enantioselective Iodine(III)‐Mediated Synthesis of α‐Tosyloxy Ketones: Breaking the Selectivity Barrier. |
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| Authors: | Basdevant, Benoit; Legault, Claude Y. |
| Source: | ChemInform ; volume 47, issue 7 ; ISSN 0931-7597 1522-2667 |
| Publisher Information: | Wiley |
| Publication Year: | 2016 |
| Collection: | Wiley Online Library (Open Access Articles via Crossref) |
| Description: | The oxidation of IPNP with MCPBA in the presence of Tos‐OH leads to a crude intermediate iodane, which reacts readily with enol acetates to afford chiral α‐tosyloxy ketones. |
| Document Type: | article in journal/newspaper |
| Language: | English |
| DOI: | 10.1002/chin.201607030 |
| Availability: | https://doi.org/10.1002/chin.201607030; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.201607030; https://onlinelibrary.wiley.com/doi/pdf/10.1002/chin.201607030 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| Accession Number: | edsbas.1A98E8EE |
| Database: | BASE |