| Title: |
Photoresponsive Dioxazaborocanes-Containing Oligomers |
| Authors: |
Eddine, Nour Nour; Meslong, Laurine; Cordier, Marie; Arroyo Diaz, Ismael; Aloïse, Stéphane; Devillard, Marc; Alcaraz, Gilles |
| Contributors: |
Institut des Sciences Chimiques de Rennes (ISCR); Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes); Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 (LASIRE); Institut de Chimie - CNRS Chimie (INC-CNRS)-Université de Lille-Centre National de la Recherche Scientifique (CNRS); ANR-19-CE06-0022,TACTIL,Nouvel fibre textile intelligente photoactivable utilisant des photocommutatuers type diarylethene(2019) |
| Source: |
ISSN: 0947-6539. |
| Publisher Information: |
CCSD; Wiley-VCH Verlag |
| Publication Year: |
2024 |
| Collection: |
LillOA (HAL Lille Open Archive, Université de Lille) |
| Subject Terms: |
Dioxazaborocane; Dithienylethene; Oligomers; Photomechanical effect; Aminoboranes; [CHIM.ORGA]Chemical Sciences/Organic chemistry; [CHIM.MATE]Chemical Sciences/Material chemistry; [CHIM.POLY]Chemical Sciences/Polymers |
| Description: |
International audience ; he synthetic methodology for the preparation of photoresponsive dioxazaborocanes-containing oligomers is developed. It relies on the transformation of the (diisopropylamino)boryl group (-BH(NiPr2)) into a dioxazaborocane unit in the presence β-aminodiols and involves a bis-borylated dithienylethene photochromic unit. The photophysical properties of the obtained oligomers are evaluated as well as their processability for the preparation of spin-coated films. The photomechanical behavior of the resulting films is assessed via displacement tracking profile. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| Relation: |
info:eu-repo/semantics/altIdentifier/pmid/39207028; PUBMED: 39207028 |
| DOI: |
10.1002/chem.202402912 |
| Availability: |
https://hal.science/hal-04684369; https://hal.science/hal-04684369v1/document; https://hal.science/hal-04684369v1/file/Non-highlighted%20revised%20Manuscript.pdf; https://doi.org/10.1002/chem.202402912 |
| Rights: |
info:eu-repo/semantics/OpenAccess |
| Accession Number: |
edsbas.21D9A9C1 |
| Database: |
BASE |