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Multiple quantum wells with ultrathin high-Sn fraction GeSn layers: Structural and optical properties

Title: Multiple quantum wells with ultrathin high-Sn fraction GeSn layers: Structural and optical properties
Authors: Ilya V. Skvortsov; Vladimir I. Mashanov; Ivan D. Loshkarev; Vyacheslav A. Timofeev; Dmitry V. Kolyada; Dmitry D. Firsov; Oleg S. Komkov; Kirill A. Lozovoy
Source: Next Materials, Vol 9, Iss , Pp 101353- (2025)
Publisher Information: Elsevier
Publication Year: 2025
Collection: Directory of Open Access Journals: DOAJ Articles
Subject Terms: Germanium-tin; Elastically strained layer; Epitaxy; Quantum well; Band structure; Photoluminescence; Technology
Description: The conditions of the formation of GeSn/Si multiple quantum wells (MQWs), including ultrathin GeSn layers with the Sn content of up to 47 %, were determined using the molecular beam epitaxy technique. The photoluminescence (PL) properties of GeSn/Si MQWs were studied in the near-infrared range. The analysis of the band diagrams of the GeSn/Si heterostructure, as well as the results of measuring the PL spectra of the Ge0.53Sn0.47/Si MQWs at different excitation densities, confirmed the formation of a type-II heterostructure. It was found that the decrease of the GeSn deposition temperature and the GeSn layer thickness leads to the increase of the PL signal associated with interband optical transitions. In addition, the significant decrease of the PL associated with vacancy complexes is observed compared to the signal from interband transitions. It was demonstrated that the most intense PL signal is observed from structures with the smallest thickness of GeSn layers of about 1 monolayer. Temperature-dependent PL studies for GeSn/Si MQWs were carried out and the activation energies of the processes leading to the temperature quenching of PL intensities were determined.
Document Type: article in journal/newspaper
Language: English
Relation: http://www.sciencedirect.com/science/article/pii/S2949822825008718; https://doaj.org/toc/2949-8228; https://doaj.org/article/5cb0125485924b7b8555aeb6ef168dc0
DOI: 10.1016/j.nxmate.2025.101353
Availability: https://doi.org/10.1016/j.nxmate.2025.101353; https://doaj.org/article/5cb0125485924b7b8555aeb6ef168dc0
Accession Number: edsbas.295DE7B3
Database: BASE