Carbene insertion into a P–H bond: parent phosphinidene–carbene adducts from PH 3 and bis(phosphinidene)mercury complexes
| Title: | Carbene insertion into a P–H bond: parent phosphinidene–carbene adducts from PH 3 and bis(phosphinidene)mercury complexes |
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| Authors: | Bispinghoff, Mark; Tondreau, Aaron M.; Grützmacher, Hansjörg; Faradji, Charly A.; Pringle, Paul G. |
| Source: | Dalton Transactions ; volume 45, issue 14, page 5999-6003 ; ISSN 1477-9226 1477-9234 |
| Publisher Information: | Royal Society of Chemistry (RSC) |
| Publication Year: | 2016 |
| Description: | The insertion of an N-heterocyclic carbene into a P–H bond is the first step in a new synthesis of parent phosphinidene–carbene adducts from PH 3 . These adducts are used to generate bis(phosphinidene)mercury(ii) complexes. |
| Document Type: | article in journal/newspaper |
| Language: | English |
| DOI: | 10.1039/c5dt01741f |
| Availability: | https://doi.org/10.1039/c5dt01741f; http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT01741F |
| Accession Number: | edsbas.2BB1E392 |
| Database: | BASE |