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Biomimetic 3D Prototyping of Hierarchically Porous Multilayered Membranes for Enhanced Oil–Water Filtration

Title: Biomimetic 3D Prototyping of Hierarchically Porous Multilayered Membranes for Enhanced Oil–Water Filtration
Authors: Kumar, Abhishek Saji; Akoumeh, Rayane; Ramanathan, Arunachalam; Park, JaeWoo; Thippanna, Varunkumar; Patil, Dhanush; Zhu, Yuxiang; Ravichandran, Dharneedar; Thummalapalli, Sri Vaishnavi; Sobczak, M Taylor; Chambers, Lindsay Bick; Theobald, Taylor G; Yu, Churan; Sui, Chao; Yang, Libin; Ponnamma, Deepalekshmi; Hassan, Mohammad K; Al-Ejji, Maryam; Yang, Sui; Song, Kenan
Source: ACS Applied Materials & Interfaces, vol 17, iss 5
Publisher Information: eScholarship, University of California
Publication Year: 2025
Collection: University of California: eScholarship
Subject Terms: 4014 Manufacturing Engineering (for-2020); 40 Engineering (for-2020); Biotechnology (rcdc); Bioengineering (rcdc); 3D printing; multilayer membrane; oil-waterfiltration; antifouling; additive manufacturing; PVDF; hierarchical structure; scalable; oil−water filtration; 03 Chemical Sciences (for); 09 Engineering (for); Nanoscience & Nanotechnology (science-metrix); 34 Chemical sciences (for-2020); 51 Physical sciences (for-2020)
Time: 8285 - 8298
Description: This study introduces a biomimetic approach to 3D printing multilayered hierarchical porous membranes (MHMs) using Direct Ink Writing (DIW) technology. Fabricated through a fast layer-by-layer printing process with varying concentrations of pore-forming agents, the produced MHMs mimic the hierarchical pore structure and filtration capabilities of natural soil systems. As a result, the 3D-printed MHMs achieved an impressive oil rejection rate of 99.02% and demonstrated exceptional reusability, maintaining a flux recovery ratio of 99.48% even after hours of continuous filtration. Moreover, the 3D-printed MHMs exhibit superior hierarchical porous architecture and mechanical integrity compared to traditional flat sheet single-layered membranes. This study presents a significant advancement for scalable 3D printing of customized multilayer membranes with tailored porosity and high-performance filtration properties. The simplicity, versatility, and cost-effectiveness of the presented manufacturing method offer a pathway for advanced design and on-demand membrane production.
Document Type: article in journal/newspaper
File Description: application/pdf
Language: unknown
Relation: qt0r37c1z7; https://escholarship.org/uc/item/0r37c1z7; https://escholarship.org/content/qt0r37c1z7/qt0r37c1z7.pdf
DOI: 10.1021/acsami.4c18528
Availability: https://escholarship.org/uc/item/0r37c1z7; https://escholarship.org/content/qt0r37c1z7/qt0r37c1z7.pdf; https://doi.org/10.1021/acsami.4c18528
Rights: CC-BY
Accession Number: edsbas.2C740630
Database: BASE