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Single-walled carbon nanotube membranes as non-reflective substrates for nanophotonic applications

Title: Single-walled carbon nanotube membranes as non-reflective substrates for nanophotonic applications
Authors: Zhigunov, Denis M.; Shilkin, Daniil A.; Kokareva, Natalia G.; Bessonov, Vladimir O.; Dyakov, Sergey A.; Chermoshentsev, Dmitry A.; Mkrtchyan, Aram A.; Gladush, Yury G.; Fedyanin, Andrey A.; Nasibulin, Albert G.
Contributors: Department of Chemistry and Materials Science; Electrochemical Energy Conversion; Skolkovo Institute of Science and Technology; Lomonosov Moscow State University; Aalto-yliopisto; Aalto University
Publisher Information: Institute of Physics Publishing
Publication Year: 2021
Collection: Aalto University Publication Archive (Aaltodoc) / Aalto-yliopiston julkaisuarkistoa
Subject Terms: carbon nanotube; free-standing thin films; scattering spectroscopy; Mie resonances; nanoparticle imaging; SILICON; NANOPARTICLES; FILMS; FABRICATION; RESONANCES; SCATTERING; NETWORKS
Description: We demonstrate that single-walled carbon nanotube (SWCNT) membranes can be successfully utilized as nanometer-thick substrates for enhanced visualization and facilitated study of individual nanoparticles. As model objects, we transfer optically resonant 200 nm silicon nanoparticles onto pristine and ethanol-densified SWCNT membranes by the femtosecond laser printing method. We image nanoparticles by scanning electron and bright-field optical microscopy, and characterize by linear and Raman scattering spectroscopy. The use of a pristine SWCNT membrane allows to achieve an order-of-magnitude enhancement of the optical contrast of the nanoparticle bright field image over the results shown in the case of the glass substrate use. The observed optical contrast enhancement is in agreement with the spectrophotometric measurements showing an extremely low specular reflectance of the pristine membrane (≤0.1%). Owing to the high transparency, negligibly small reflectance and thickness, SWCNT membranes offer a variety of perspective applications in nanophotonics, bioimaging and synchrotron radiation studies. ; Peer reviewed
Document Type: article in journal/newspaper
File Description: application/pdf
Language: English
Relation: Nanotechnology; Volume 32, issue 9; We are grateful to Alexander Ezhov, Evgeny Lyubin, Dmitry Dzhigaev and Ivan Filippov for their help with experiments and valuable suggestions. DMZ and DAS acknowledge the support of the Russian Foundation for Basic Research (Project No. 18-32-20217, optical microscopy measurements). DAS, NGK, VOB, AAF acknowledge the support of the Ministry of Education and Science of the Russian Federation (Project No. 14.W03.31.0008, fabrication of nanoparticles) and MSU Quantum Technology Center. DAS acknowledges the support of the Russian Science Foundation (Project No. 18-72-00247, linear scattering spectroscopy measurements). SAD and Yu GG thank Russian Foundation for Basis Research (Project No. 18-29-20032, simulation of optical properties). AGN acknowledges the support of Ministry of Education and Science of the Russian Federation (Project No. 0679-2020-0007 (FZSR-2020-0007) in the framework of state assignment No. 075-03-2020-097/1, SWCNT membrane fabrication).; PURE FILEURL: https://research.aalto.fi/files/54443539/CHEM_Zhigunov_et_al_Single_walled_carbon_nanotube_membranes_Nanotechnology.pdf; https://aaltodoc.aalto.fi/handle/123456789/101588
DOI: 10.1088/1361-6528/abcacc
Availability: https://aaltodoc.aalto.fi/handle/123456789/101588; https://doi.org/10.1088/1361-6528/abcacc
Rights: openAccess
Accession Number: edsbas.2DAF73A
Database: BASE