| Title: |
An Improved Manganese Pincer Catalyst for low Temperature Hydrogenation of Carbon Monoxide to Methanol |
| Authors: |
Neitzel, Gordon; Razzaq, Rauf; Spannenberg, Anke; Stier, Kenta; Checinski, Marek P.; Jackstell, Ralf; Beller, Matthias |
| Source: |
ChemCatChem ; volume 16, issue 4 ; ISSN 1867-3880 1867-3899 |
| Publisher Information: |
Wiley |
| Publication Year: |
2024 |
| Collection: |
Wiley Online Library (Open Access Articles via Crossref) |
| Description: |
A manganese pincer complex Mn‐2 for the homogeneously catalysed conversion of CO/H 2 to methanol was developed using a novel PNP ligand design. Compared to the previous state‐of‐the‐art catalyst system Mn‐1, the presented Mn‐2 with different substituents at the P‐atoms led to a significant increase of the reaction rate (TOF up to >1600 h −1 ). |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1002/cctc.202301053 |
| Availability: |
https://doi.org/10.1002/cctc.202301053 |
| Rights: |
http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| Accession Number: |
edsbas.2F6FD496 |
| Database: |
BASE |