| Title: |
1,3-Bis(2,6-diisopropylphenyl)-2-trichloromethylimidazolidine |
| Authors: |
Stack, Darcie L.; Masuda, Jason Douglas, 1977- |
| Publisher Information: |
MDPI |
| Publication Year: |
2017 |
| Collection: |
Saint Mary's University, Halifax: Institutional Repository |
| Subject Terms: |
Chloroform; Heterocyclic compounds; Carbenes (Methylene compounds) |
| Description: |
Published Version ; A new chloroform adduct of the N-heterocyclic carbene (NHC) 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene (SIPr) has been prepared via C–H bond activation of the chloroform at the carbene carbon. This redox product was crystallized and was characterized by 1 H and 13 C-NMR spectroscopy, elemental analysis (EA), and single-crystal X-ray diffraction. The 1 H and 13 C-NMR spectroscopic data are in agreement with the crystal structure. Density functional theory (DFT) calculations were performed as a means for comparison to experimental data and the computational results are in agreement with those obtained experimentally. |
| Document Type: |
text |
| File Description: |
application/pdf |
| Language: |
English |
| Relation: |
http://library2.smu.ca/xmlui/handle/01/29788 |
| Availability: |
http://library2.smu.ca/xmlui/handle/01/29788 |
| Rights: |
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| Accession Number: |
edsbas.3011CCEE |
| Database: |
BASE |