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Preparation and Characterization of Ni/H-ZSM-5 Catalysts for Producing Green Diesel from Palmitic Acid

Title: Preparation and Characterization of Ni/H-ZSM-5 Catalysts for Producing Green Diesel from Palmitic Acid
Authors: Kurniati, Sayekti; Azis, Muhammad Mufti; Dwiatmoko, Adid Adep
Source: Seminar Nasional Teknik Kimia "Kejuangan"; 2023: PROSIDING SNTKK 2023; E1.1-E1.5 ; Prosiding Seminar Nasional Teknik Kimia "Kejuangan"; 2023: PROSIDING SNTKK 2023; E1.1-E1.5
Publisher Information: Seminar Nasional Teknik Kimia "Kejuangan"; Prosiding Seminar Nasional Teknik Kimia "Kejuangan"
Publication Year: 2023
Collection: UPN (Universitas Pembangunan Nasional) Veteran Yogyakarta: Portal Journals
Subject Terms: green diesel; nickel catalyst; H-ZSM-5; acid sites
Description: Biofuel is a promising alternative as a sustainable energy resource in the transportation sector in Indonesia. Green diesel is one of biofuels that can be produced from feedstock containing fatty acid. Fatty acid conversion to green diesel can be conducted via hydrodecarboxylation or hydrodeoxygenation process. Catalyst Ni/H-ZSM-5 is a potential catalyst to convert fatty acid to n-alkane which is the main component in green diesel. In this work, we prepared Ni/H-ZSM-5 catalyst with various Ni loading of 7%, 13%, 18%, and 25%, respectively. The catalysts were synthesized according to a simple incipient wetness impregnation method. Those catalysts were characterized with X-ray fluorescence, Field-Emission Scanning Electron Microscopy, and NH3-TPD. The highest nickel-loading catalyst, Ni 25%/H-ZSM-5, gave the best dispersion. NH3-TPD results showed the presence of two acid sites, namely Brønsted acid site and Lewis acid site. The presence of Brønsted acid sites is crucial to facilitate fatty acid conversion to n-alkane.
Document Type: article in journal/newspaper
File Description: application/pdf
Language: English
Relation: https://jurnal.upnyk.ac.id/index.php/kejuangan/article/view/10290/5568; https://jurnal.upnyk.ac.id/index.php/kejuangan/article/view/10290
Availability: https://jurnal.upnyk.ac.id/index.php/kejuangan/article/view/10290
Rights: Copyright (c) 2023 Seminar Nasional Teknik Kimia "Kejuangan"
Accession Number: edsbas.30338250
Database: BASE