| Title: |
Preparation of methylammonium lead iodide (CH₃NH₃PbI₃) thin film perovskite solar cells by chemical vapor deposition using methylamine gas (CH₃NH₂) and hydrogen iodide gas |
| Authors: |
Mortan, Claudiu; Hellmann, Tim; Buchhorn, Moritz; Melzi d'Eril, Marco; Clemens, Oliver; Mayer, Thomas; Jaegermann, Wolfram |
| Publisher Information: |
John Wiley & Sons |
| Publication Year: |
2024 |
| Collection: |
TU Darmstadt: tuprints |
| Description: |
An upscalable chemical vapor deposition setup has been built‐up and employed in producing methylammonium lead iodide (MAPI) thin film perovskite solar cells, leading to a maximum efficiency of 12.9%. The method makes use of methylamine gas and hydrogen iodide gas to transform a predeposited layer of lead(II)iodide (PbI₂) into MAPI. Although the reaction mechanism includes the intermediate phases lead oxide (PbO) and lead hydroxide (Pb(OH)₂), indicated at least on the surface of the samples by XPS, neither species could be observed in XRD measurements of the stepwise reaction, which show a mixture of highly oriented cubic and tetragonal MAPI perovskite lattice systems. |
| Document Type: |
article in journal/newspaper |
| File Description: |
text |
| Language: |
English |
| Relation: |
https://tuprints.ulb.tu-darmstadt.de/16175/1/ESE3_ESE3734.pdf; https://tuprints.ulb.tu-darmstadt.de/16175/7/ese3734-sup-0001-supinfo.docx; Mortan, Claudiu; Hellmann, Tim; Buchhorn, Moritz; Melzi d'Eril, Marco; Clemens, Oliver; Mayer, Thomas; Jaegermann, Wolfram (2024)Preparation of methylammonium lead iodide (CH₃NH₃PbI₃) thin film perovskite solar cells by chemical vapor deposition using methylamine gas (CH₃NH₂) and hydrogen iodide gas. In: Energy Science & Engineering, 2020, 8 (9) doi:10.26083/tuprints-00016175 Article, Secondary publication, Publisher's Version |
| DOI: |
10.26083/tuprints-00016175 |
| Availability: |
http://tuprints.ulb.tu-darmstadt.de/16175/; https://doi.org/10.26083/tuprints-00016175 |
| Rights: |
CC BY 4.0 International - Creative Commons, Attribution ; info:eu-repo/semantics/openAccess |
| Accession Number: |
edsbas.33AEDCF9 |
| Database: |
BASE |