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Multistep sintering: its role on density, phase homogeneity, microstructure and electrical properties of (1-x-y)BaTiO 3 -xPbZrO3-yNaVO3 System

Title: Multistep sintering: its role on density, phase homogeneity, microstructure and electrical properties of (1-x-y)BaTiO 3 -xPbZrO3-yNaVO3 System
Authors: Absa, M; Latief, F; Suasmoro, S
Source: Journal of Physics: Conference Series ; volume 1825, issue 1, page 012063 ; ISSN 1742-6588 1742-6596
Publisher Information: IOP Publishing
Publication Year: 2021
Description: Barium Titanate synthesized by the oxalate coprecipitation method was doped by other perovskite-based material PbZrO 3 and NaVO 3 to obtain a system of (1-x-y)BaTiO 3 -xPbZrO 3 -yNaVO 3 with x = 0.15 and y = 0.025. TGA characterization shows an important weight loss that starts at 400°C and finished at 650°C. XRD analysis of calcined powder at 650°C shows that the samples mostly consist of single-phase BaTiO 3 perovskite. Sintering process was carried out in two ways; first, a single step sintering up to 1250°C for 2 hours shows increasing secondary phases, until the BaTiO 3 phase becomes the minority. Secondly, multistep sintering starting at 1050°C, holding for 2 hours, down to room temperature, and then repeated with similar processes for 1150°C and 1250°C. Characterizations including XRD, SEM for microstructure, and permittivity analysis of the sample after this thermal treatment shows that the majority phase is BaTiO 3 with minor secondary BaVO 2.9 phase and its electrical properties are enhanced.
Document Type: article in journal/newspaper
Language: unknown
DOI: 10.1088/1742-6596/1825/1/012063
DOI: 10.1088/1742-6596/1825/1/012063/pdf
Availability: https://doi.org/10.1088/1742-6596/1825/1/012063; https://iopscience.iop.org/article/10.1088/1742-6596/1825/1/012063; https://iopscience.iop.org/article/10.1088/1742-6596/1825/1/012063/pdf
Rights: http://creativecommons.org/licenses/by/3.0/ ; https://iopscience.iop.org/info/page/text-and-data-mining
Accession Number: edsbas.381B1C34
Database: BASE