| Title: |
Induction of Supramolecular Helical Handedness in a Chemical Reaction Directed Self‐Healable Soft Material |
| Authors: |
Reja, Antara; Biswas, Ankan; Yadav, Jonu; Dev, Dharm; Das, Apurba K. |
| Contributors: |
Department of Science & Technology |
| Source: |
ChemistrySelect ; volume 2, issue 34, page 10984-10989 ; ISSN 2365-6549 2365-6549 |
| Publisher Information: |
Wiley |
| Publication Year: |
2017 |
| Collection: |
Wiley Online Library (Open Access Articles via Crossref) |
| Description: |
Thixotropic and self‐healable supramolecular gel with nanohelical morphological features of discotic C 3 symmetric benzene‐1,3,5‐tricarboxylic acid coupled with (L)‐ and (D)‐phenylalanine were achieved by hydroxyl anion catalysed methyl ester hydrolysis in presence of lithium ions. The hydrolysis of methyl ester and subsequent formation of gel are highly dependent on metal ions. The arrangement of the molecular building blocks and increasing the structural complexity during the origin of the supramolecular structures from the monomeric units by a chemical reaction act as the executive parameters to determine the handedness of macroscopic chirality. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1002/slct.201702212 |
| DOI: |
10.1002/slct.201702212/fullpdf |
| Availability: |
https://doi.org/10.1002/slct.201702212; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fslct.201702212; http://onlinelibrary.wiley.com/wol1/doi/10.1002/slct.201702212/fullpdf |
| Rights: |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
| Accession Number: |
edsbas.39C33E6D |
| Database: |
BASE |