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A techno-economic comparison of biological and chemical routes for CO2 methanation in renewable LNG production

Title: A techno-economic comparison of biological and chemical routes for CO2 methanation in renewable LNG production
Authors: Visonà, Marco; Orellana, Esteban; Treu, Laura; Barbera, Elena
Contributors: Visonà, Marco; Orellana, Esteban; Treu, Laura; Barbera, Elena
Publisher Information: Elsevier Ltd
Publication Year: 2026
Collection: Padua Research Archive (IRIS - Università degli Studi di Padova)
Subject Terms: Anaerobic digestion; Biomethanation; Liquefied Natural Ga; Power-to-ga; Process simulation
Description: Liquefied Natural Gas (LNG) has recently emerged as a promising substitute maritime fuel, due to its potential of reducing GHG emissions with respect to heavy fuel oils. This paper analyses and compares from a techno-economic point of view different technological pathways for renewable LNG production to be used as bunker fuel in North-Eastern Italy. Specifically, CO2 hydrogenation (a process also known as methanation) is considered, either starting from carbon dioxide captured from industrial flue gases (e-LNG), or from the biogas obtained via anaerobic digestion of biomass (bio-LNG). Moreover, both chemical (via the Sabatier reaction) and biological (exploiting hydrogenotrophic microorganisms) methanation have been considered. Results show that the bio-LNG route is more economically feasible with a Levelized Cost of Methane (LCOM) of about 150 €/MWh, but feedstock availability strongly limits the LNG throughput. On the other hand, the e-LNG route can reach larger production capacity, with a LCOM of around 200 €/MWh. Biological methanation is currently slightly less profitable compared to the chemical route mainly due to large investment costs, however technological advancements could significantly improve the economic performances.
Document Type: article in journal/newspaper
Language: English
Relation: info:eu-repo/semantics/altIdentifier/wos/WOS:001696434800001; volume:106; journal:JOURNAL OF CO2 UTILIZATION; https://hdl.handle.net/11577/3586259
DOI: 10.1016/j.jcou.2026.103368
Availability: https://hdl.handle.net/11577/3586259; https://doi.org/10.1016/j.jcou.2026.103368
Rights: info:eu-repo/semantics/openAccess ; license:Creative commons ; license uri:http://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.41EAA49E
Database: BASE