| Title: |
Synthesis and structures of [((Me3Si)(3)CAlF2)(2)(mu-O)Li-2(THF)(4)] and [{Li(Me3Si)(3)CAlF3(THF)}(3)LiF(THF)] |
| Authors: |
Hatop, H.; Schiefer, M.; Roesky, H. W.; Herbst-Irmer, R.; Labahn, T. |
| Contributors: |
Hatop, H.; Schiefer, M.; Roesky, H. W.; Herbst-Irmer, R.; Labahn, T. |
| Publisher Information: |
Amer Chemical Soc |
| Publication Year: |
2001 |
| Collection: |
Georg-August-Universität Göttingen: GoeScholar |
| Description: |
The synthesis of [((Me3Si)(3)CAlF2)(2)(mu -O)Li-2- (THF)(4)] (1) and [{Li(Me3Si)(3)CAlF3(THF)}(3)LiF(THF)] (2) is reported. Compound 1 was obtained either by the reaction of (Me3Si)(3)CAlMe2. THF and Me3SnF in the presence of Li2O or by the reaction of [(Me3Si)(3)CAlF2](3) and Li2O. 1 is an interesting example of an oxygen- and fluorine-containing alkyl aluminum compound. Complex 2 was prepared by the reaction of (Me3Si)(3)CAlF2. THF with LiOCH(CF3)(2) as an unexpected result that illustrates the variety of possible structures obtainable by the combination of [(Me3Si)(3)CAlF2](3) and LiF. |
| Document Type: |
article in journal/newspaper |
| Language: |
unknown |
| Relation: |
000169242700036 |
| DOI: |
10.1021/om0100941 |
| Availability: |
https://resolver.sub.uni-goettingen.de/purl?gro-2/23710; https://doi.org/10.1021/om0100941 |
| Rights: |
info:eu-repo/semantics/openAccess |
| Accession Number: |
edsbas.4AAA2E1A |
| Database: |
BASE |