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Further investigations into alloy induced acidic fluxing

Title: Further investigations into alloy induced acidic fluxing
Authors: Potter, Andrew; Sumner, Joy; Simms, Nigel
Publisher Information: Taylor and Francis
Publication Year: 2023
Collection: Cranfield University: Collection of E-Research - CERES
Subject Terms: Type II hot corrosion; superalloys; alloy-induced acidic fluxing; mixed mode hot corrosion
Description: Gas turbine materials often feature precipitates containing refractory metals to enhance their mechanical strength. This can make them susceptible to alloy-induced acidic fluxing whereby refractory elements increase the acidity of salt deposits. It is not clear to what degree degradation around alloy precipitates is caused by alloy-induced hot corrosion mechanisms, or the inability to develop a protective scale where precipitates are located. The effect of alloy-induced hot corrosion was isolated from the disruption of the protective-scale formation by adding particles of molybdenum to the 80/20 (Na/K)2SO4 deposit for a ‘deposit re-coat’ style hot corrosion test. The resulting morphologies were compared to samples exposed without the addition of molybdenum. Morphology changes were investigated using scanning electron microscopy with energy-dispersive X-ray mapping. Results show a mix of sulphidation and pitting. The effects of molybdenum additions appear more severe for MarM 509 compared to PWA 1483. ; Materials at High Temperature
Document Type: article in journal/newspaper
File Description: pp. 338-347; application/pdf
Language: English
Relation: https://doi.org/10.1080/09603409.2023.2219877; https://dspace.lib.cranfield.ac.uk/handle/1826/19912; 40
DOI: 10.1080/09603409.2023.2219877
Availability: https://doi.org/10.1080/09603409.2023.2219877; https://dspace.lib.cranfield.ac.uk/handle/1826/19912
Rights: Attribution 4.0 International ; http://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.4BB33AE9
Database: BASE