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Hydrophilization of rice seeds by plasma treatments – Super-hydrophilic surface finish and hydrophobic recovery

Title: Hydrophilization of rice seeds by plasma treatments – Super-hydrophilic surface finish and hydrophobic recovery
Authors: Vesel A.; Macovei A.; Balestrazzi A.; Gupta Tondepu S. A.; Duenas C.; Locato V.; Tonto T. C.; Zoani C.; Lojen D.; Primc G.; Zaplotnik R.; Ogrinc N.; Lehocky M.; Mozetic M.
Contributors: Vesel, A.; Macovei, A.; Balestrazzi, A.; Gupta Tondepu, S. A.; Duenas, C.; Locato, V.; Tonto, T. C.; Zoani, C.; Lojen, D.; Primc, G.; Zaplotnik, R.; Ogrinc, N.; Lehocky, M.; Mozetic, M.
Publication Year: 2025
Collection: IRIS UNIPV (Università degli studi di Pavia)
Subject Terms: Rice seed; Water adsorption; Germination; Surface treatment; Wettability; Super-hydrophilicity
Description: The hydrophobic character of rice seeds protects them from quick water adsorption and, thus, premature germination. This property is, however, a drawback in modern agriculture, where rapid and uniform germination represents a high-quality trait. A method for rapid hydrophilization of the Lomello variety of rice is presented. The rice seeds were treated with low-pressure gaseous plasma to tailor the wettability. The treatment of seeds with hulls with oxygen plasma afterglow enabled the super-hydrophilic surface finish within 10 ms. Such extremely fast hydrophilization was attributed to irreversible surface oxidation by neutral oxygen atoms whose flux onto the seeds was approximately 3 x 10(23) m(-2)s(-1). Dehulled seeds were made super-hydrophilic by subsequent treatments with hydrogen and oxygen plasma, and the required dose of O atoms was between 2 x 10(23) and 6 x 10(24) m(-2). Larger doses caused a loss of the super-hydrophilicity. Hydrophilization kinetics is proposed and supported by measuring surface wettability, morphology, and composition using various techniques. The hydrophobic recovery of seeds with hulls is marginal within the first few days after plasma treatments, but dehulled seeds lose the super-hydrophilic surface finish within a few minutes after the plasma treatment when stored at ambient conditions.
Document Type: article in journal/newspaper
Language: English
Relation: info:eu-repo/semantics/altIdentifier/wos/WOS:001510789500001; volume:691; journal:APPLIED SURFACE SCIENCE; https://hdl.handle.net/11571/1529395
DOI: 10.1016/j.apsusc.2025.162674
Availability: https://hdl.handle.net/11571/1529395; https://doi.org/10.1016/j.apsusc.2025.162674
Accession Number: edsbas.4D3836EF
Database: BASE