| Title: |
A new strategy for the stereoselective synthesis of 1,2,3-trisubstituted cyclopropanes |
| Authors: |
Bohm C.; Schinnerl M.; Bubert C.; Zabel M.; Labahn T.; Parisini E.; Reiser O. |
| Contributors: |
Bohm C.; Schinnerl M.; Bubert C.; Zabel M.; Labahn T.; Parisini E.; Reiser O. |
| Publication Year: |
2000 |
| Collection: |
IRIS Università degli Studi di Bologna (CRIS - Current Research Information System) |
| Subject Terms: |
Aldol reaction; Amino aldehyde; Donor-acceptor cyclopropane; Felkin-Anh rule; Nucleophilic additions |
| Description: |
The stereoselective synthesis of highly functionalized 1,2,3-trisubstituted cyclopropanes 1 and 2, starting from readily available furans 3 or N-protected pyrrole 4, is described. Furthermore, exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the title compounds. |
| Document Type: |
article in journal/newspaper |
| File Description: |
ELETTRONICO |
| Language: |
English |
| Relation: |
volume:2000; issue:16; firstpage:2955; lastpage:2965; numberofpages:11; journal:EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; https://hdl.handle.net/11585/916190 |
| Availability: |
https://hdl.handle.net/11585/916190 |
| Accession Number: |
edsbas.52035A76 |
| Database: |
BASE |