| Title: |
On the Importance of Chemical Precision in Organic Electronics: Fullerene Intercalation in Perfectly Alternating Conjugated Polymers |
| Authors: |
VANDERSPIKKEN, Jochen; Liu, Zhen; Wu, Xiaocui; BECKERS, Omar; Moro, Stefania; Quill, Tyler James; LIU, Quan; GOOSSENS, Arwin; Marks, Adam; Weaver, Karrie; Hamid, Mouna; Goderis, Bart; Nies, Erik; Lemaur, Vincent; Beljonne, David; Salleo, Alberto; LUTSEN, Laurence; VANDEWAL, Koen; Van Mele, Bruno; Costantini, Giovanni; Van den Brande, Niko; MAES, Wouter |
| Contributors: |
VANDERSPIKKEN, Jochen; Liu, Zhen; Wu, Xiaocui; BECKERS, Omar; Moro, Stefania; Quill, Tyler James; LIU, Quan; GOOSSENS, Arwin; Marks, Adam; Weaver, Karrie; Hamid, Mouna; Goderis, Bart; Nies, Erik; Lemaur, Vincent; Beljonne, David; Salleo, Alberto; LUTSEN, Laurence; VANDEWAL, Koen; Van Mele, Bruno; Costantini, Giovanni; Van den Brande, Niko; MAES, Wouter |
| Publication Year: |
2023 |
| Collection: |
Document Server@UHasselt (Universiteit Hasselt) |
| Subject Terms: |
homocoupling; intermolecular charge-transfer absorption; polymer:fullerene co-crystals; Stille cross-coupling; structural defect quantification |
| Description: |
The true structure of alternating conjugated polymers-the state-of-the-art materials for many organic electronics-often deviates from the idealized picture. Homocoupling defects are in fact inherent to the widely used cross-coupling polymerization methods. Nevertheless, many polymers still perform excellently in the envisaged applications, which raises the question if one should really care about these imperfections. This article looks at the relevance of chemical precision (and lack thereof) in conjugated polymers covering the entire spectrum from the molecular scale, to the micro and mesostructure, up to the device level. The different types of polymerization errors for the alkoxylated variant of the benchmark (semi)crystalline polymer poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene (PBTTT) are identified, visualized, and quantified and a general strategy to avoid homocoupling is introduced. Through a combination of experiments and supported by simulations, it is shown that these coupling defects hinder fullerene intercalation and limit device performance as compared to the homocoupling-free analog. This clearly demonstrates that structural defects do matter and should be generally avoided, in particular when the geometrical regularity of the polymer is essential. These insights likely go beyond the specific PBTTT derivatives studied here and are of general relevance for the wider organic electronics field. ; The authors thank the FWO Vlaanderen (Ph.D. and travel grant J.V. (1S50822N and V413722N), projects G0D0118N and G0B2718N, MALDIToF project I006320N, DUBBLE project I001919N, Scientific Research Community “Supramolecular Chemistry and Materials” ‒ W000620N) and the European Research Council (grant 864625) for financial support. J.V. received a personal grant from District 1630 of Rotary International, supported by the Rotary Foundation, allowing a student researcher to visit Stanford University. X.W. acknowledges co-funding from the European Union’s Horizon 2020 research and innovation Marie ... |
| Document Type: |
article in journal/newspaper |
| File Description: |
application/pdf |
| Language: |
English |
| Relation: |
info:eu-repo/grantAgreement/EC/H2020/964677; ADVANCED FUNCTIONAL MATERIALS, (Art N° 2309403); https://hdl.handle.net/1942/41414; 001064802500001 |
| DOI: |
10.1002/adfm.202309403 |
| Availability: |
https://hdl.handle.net/1942/41414; https://doi.org/10.1002/adfm.202309403 |
| Accession Number: |
edsbas.55B756E8 |
| Database: |
BASE |