| Title: |
Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
| Authors: |
Siidra, Oleg I; Nazarchuk, Evgeny V; Charkin, Dmitry O; Chukanov, Nikita V; Depmeier, Wulf; Bocharov, Sergey N; Sharikov, Mikhail I |
| Publication Year: |
2018 |
| Collection: |
Christian-Albrechts-Universität zu Kiel: MACAU |
| Subject Terms: |
article; ScholarlyArticle; ddc:540; ddc:530; Published Version; Uranium; Sulfates; Nanotubes; Nanostructured Materials; Actinide Materials; Microporous Compounds; Organically Templated Compounds |
| Description: |
The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH⁺)₇[(UO₂)₆(SO₄)10](H₂O)3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO₂)₆(SO₄)10]8- nanotubules templated by protonated N-phenylglycine (C₆H₅NH₂CH₂COOH)⁺. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO₄ tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| Relation: |
Nanomaterials (Basel, Switzerland) -- Nanomaterials (Basel) -- 2079-4991 -- 2079-4991; https://doi.org/10.3390/nano8040216 |
| DOI: |
10.3390/nano8040216 |
| Availability: |
https://doi.org/10.3390/nano8040216; https://nbn-resolving.org/urn:nbn:de:gbv:8-mods-2019-00149-0; https://macau.uni-kiel.de/receive/macau_mods_00000110; https://macau.uni-kiel.de/servlets/MCRFileNodeServlet/macau_derivate_00001059/nanomaterials-08-00216-v3.pdf |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ ; info:eu-repo/semantics/openAccess |
| Accession Number: |
edsbas.580DCB19 |
| Database: |
BASE |