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Interfacial energy between carbon nanotubes and polymers measured from nanoscale peel tests in the atomic force microscope

Title: Interfacial energy between carbon nanotubes and polymers measured from nanoscale peel tests in the atomic force microscope
Authors: Strus, Mark C; Cano, Camilo I; Pipes, R. Byron; Nguyen, Cattien V.; Raman, Arvind
Source: Other Nanotechnology Publications
Publisher Information: Purdue University
Publication Year: 2009
Collection: Purdue University: e-Pubs
Subject Terms: nanoscale peeling; carbon nanotubes; polymer nanocomposites; interfacial fracture energy; atomic force microscope; surface energy; Applied Mechanics; Materials Science and Engineering; Mechanical Engineering; Nanoscience and Nanotechnology; Polymer and Organic Materials
Description: The future development of polymer composite materials with nanotubes or nanoscale fibers requires the ability to understand and improve the interfacial bonding at the nanotube-polymer matrix interface. In recent work [Strus MC, Zalamea L, Raman A, Pipes RB, Nguyen CV, Stach EA. Peeling force spectroscopy: exposing the adhesive nanomechanics of one-dimensional nanostructures. Nano Lett 2008;8(2):544–50], it has been shown that a new mode in the Atomic Force Microscope (AFM), peeling force spectroscopy, can be used to understand the adhesive mechanics of carbon nanotubes peeled from a surface. In the present work, we demonstrate how AFM peeling force spectroscopy can be used to distinguish between elastic and interfacial components during a nanoscale peel test, thus enabling the direct measurement of interfacial energy between an individual nanotube or nanofiber and a given material surface. The proposed method provides a convenient experimental framework to quickly screen different combinations of polymers and functionalized nanotubes for optimal interfacial strength.
Document Type: text
File Description: application/pdf
Language: unknown
Relation: https://docs.lib.purdue.edu/nanodocs/164; https://docs.lib.purdue.edu/context/nanodocs/article/1160/viewcontent/Strus___Interfacial_energy_between_CNTs_and_polymers_measure_from_nanoscale_peel_tests_in_the_AFM.pdf
Availability: https://docs.lib.purdue.edu/nanodocs/164; https://docs.lib.purdue.edu/context/nanodocs/article/1160/viewcontent/Strus___Interfacial_energy_between_CNTs_and_polymers_measure_from_nanoscale_peel_tests_in_the_AFM.pdf
Accession Number: edsbas.588F6715
Database: BASE