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Two-Dimensional Wetting of a Stepped Copper Surface.

Title: Two-Dimensional Wetting of a Stepped Copper Surface.
Authors: Lin, C; Avidor, N; Corem, G; Godsi, O; Alexandrowicz, G; Darling, GR; Hodgson, A
Publisher Information: American Physical Society (APS); //doi.org/10.1103/physrevlett.120.076101
Publication Year: 2018
Collection: Apollo - University of Cambridge Repository
Subject Terms: 40 Engineering; 49 Mathematical Sciences; 51 Physical Sciences
Description: Highly corrugated, stepped surfaces present regular 1D arrays of binding sites, creating a complex, heterogeneous environment to water. Rather than decorating the hydrophilic step sites to form 1D chains, water on stepped Cu(511) forms an extended 2D network that binds strongly to the steps but bridges across the intervening hydrophobic Cu(100) terraces. The hydrogen-bonded network contains pentamer, hexamer, and octomer water rings that leave a third of the stable Cu step sites unoccupied in order to bind water H down close to the step dipole and complete three hydrogen bonds per molecule. ; Herchel Smith fund
Document Type: article in journal/newspaper
File Description: Print; application/pdf
Language: English
Relation: https://www.repository.cam.ac.uk/handle/1810/292106
DOI: 10.17863/CAM.39261
Availability: https://www.repository.cam.ac.uk/handle/1810/292106; https://doi.org/10.17863/CAM.39261
Rights: All rights reserved
Accession Number: edsbas.5FDD0F34
Database: BASE