| Title: |
Interphasic separation of cis/trans perylene-based nanographene isomers driven by selective encapsulation in a supramolecular cage |
| Authors: |
Fuertes Espinosa, Carles; Sabrià, Clara; Sala, Judith; Capdevila Güell, Lorena; Feixas Geronès, Ferran; Ribas Salamaña, Xavi |
| Contributors: |
Agencia Estatal de Investigación |
| Source: |
Chemical Communications, 2026, vol. 62, núm. 8, p. 2672-2676 ; Articles publicats (D-Q) |
| Publisher Information: |
Royal Society of Chemistry |
| Publication Year: |
2026 |
| Collection: |
Universitat de Girona: DUGiDocs (UdG Digital Repository) |
| Subject Terms: |
Hidrocarburs aromàtics policíclics; Reconeixement molecular; Polycyclic aromatic hydrocarbons; Molecular recognition |
| Description: |
The present work describes a supramolecular strategy for the molecular recognition and selective separation of extended PAHs and NGs from isomeric mixtures. This approach consists of a biphasic protocol featuring the selective shuttling of a targeted NG isomer from the organic to the aqueous phase, driven by host–guest interactions with a tetragonal prismatic metal–organic cage (MOC) present in the aqueous layer, while the cage remains permanently confined to the aqueous phase, operating as a static supramolecular receptor throughout the separation process. ; This work was supported by MCIN Spain (PID2022-136970NB-I00 and TED2021-130573B-I00 to X.R., RYC2020-029552-I, and PID2022-141676NB-I00 to F. F.) and Generalitat de Catalunya (2021SGR00475, 2021SGR00487) |
| Document Type: |
article in journal/newspaper |
| File Description: |
application/pdf |
| Language: |
English |
| ISSN: |
1359-7345; 1364-548X |
| Relation: |
info:eu-repo/semantics/altIdentifier/issn/1359-7345; info:eu-repo/semantics/altIdentifier/eissn/1364-548X; info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-136970NB-I00/ES/FUNCIONALIZACION REGIOSELECTIVA DE MOLECULAS ESFERICAS CON MASCARAS SUPRAMOLECULARES Y SINTESIS BOTTOM-UP DE NANOGRAFENOS/; https://hdl.handle.net/10256/28385 |
| Availability: |
https://hdl.handle.net/10256/28385 |
| Rights: |
Attribution-NonCommercial 4.0 International ; http://creativecommons.org/licenses/by-nc/4.0/ ; info:eu-repo/semantics/openAccess |
| Accession Number: |
edsbas.6C0F59F7 |
| Database: |
BASE |