Correlated solvent coordinates accelerate multi-donor proton-coupled electron transfer
| Title: | Correlated solvent coordinates accelerate multi-donor proton-coupled electron transfer |
|---|---|
| Authors: | Manbeck, Gerald F.; DiMarco, Brian N.; Rotundo, Laura; Polyansky, Dmitry E.; Ertem, Mehmed Z. |
| Contributors: | Basic Energy Sciences; U.S. Department of Energy; Brookhaven National Laboratory |
| Source: | Chemical Science ; volume 17, issue 3, page 1703-1720 ; ISSN 2041-6520 2041-6539 |
| Publisher Information: | Royal Society of Chemistry (RSC) |
| Publication Year: | 2026 |
| Description: | Multiple donors accelerate intramolecular PCET rates beyond statistical predictions. The partial sharing of solvent polarization between equivalent sites lowers the effective outer sphere reorganization energy. |
| Document Type: | article in journal/newspaper |
| Language: | English |
| DOI: | 10.1039/d5sc06787a |
| Availability: | https://doi.org/10.1039/d5sc06787a; http://pubs.rsc.org/en/content/articlepdf/2026/SC/D5SC06787A |
| Rights: | http://creativecommons.org/licenses/by-nc/3.0/ |
| Accession Number: | edsbas.6E6E75C8 |
| Database: | BASE |