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Particle response during the yielding transition of colloidal glasses

Title: Particle response during the yielding transition of colloidal glasses
Authors: Denisov, D. V.; Dang, M. T.; Struth, B.; Wegdam, G. H.; Schall, P.
Publication Year: 2014
Collection: ArXiv.org (Cornell University Library)
Subject Terms: Soft Condensed Matter
Description: Yielding is central to the relaxation, flow and fracture of a wide range of soft and molecular glasses, but its microscopic origin remains unclear. Here, we elucidate the yielding of a colloidal glass by using x-ray scattering to monitor the structure factor during the yielding process. We apply a recently introduced combination of small-angle x-ray scattering and rheology to the oscillatory shear, and follow the structure factor during the increasing strain amplitude. Surprisingly, we observe a sharp transition in the orientational ordering of the nearest-neighbor structure upon yielding, in contrast to the smooth variation of the viscoelastic moduli. This transition is accompanied by a sudden change of intensity fluctuations towards Gaussian distributions. We thus identify yielding as a new, dynamically induced transition of the glass in response to the applied shear. ; 5 pages, 4 figures
Document Type: text
Language: unknown
Relation: http://arxiv.org/abs/1401.2106
Availability: http://arxiv.org/abs/1401.2106
Accession Number: edsbas.728682E4
Database: BASE