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Investigation of the reaction of dimedone with aromatic aldehydes in the presence of copper oxide nanoparticles

Title: Investigation of the reaction of dimedone with aromatic aldehydes in the presence of copper oxide nanoparticles
Authors: Meena, Ravina; Sachdeva, Harshita
Source: Chimica Techno Acta; Том 11, № 3 (2024); 202411303 ; 2411-1414
Publisher Information: Ural Federal University
Publication Year: 2024
Collection: Ural Federal University: URFU Journal Systems / Журнальный портал УРФУ
Subject Terms: biscyclohexenone; solvent-free; recyclable; heterogeneous; CuO nanoparticles; Grindstone chemistry
Description: Variously substituted methylene bis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) derivatives were synthesized in 83–96% yield by the reaction of substituted benzaldehyde with 5, 5-dimethyl-1, 3-cyclohexanedione in the presence of CuO nanoparticles (NPs). Tandem grinding involves Knoevenagel condensation followed by the Michael addition in sequence for the formation of 2, 2’-arylmethylenebis (3-hydroxy-5, 5-dimethyl-2-cyclohexene-1-one) derivatives. Copper oxide NPs were synthesized by sol-gel method. The characterization of CuO NPs was done on the basis of PXRD, FTIR, SEM and TEM techniques. The synthesized derivatives were characterized on the basis of spectral analyses and corresponding melting points reported in the literature.
Document Type: article in journal/newspaper
File Description: application/pdf
Language: English
Relation: https://chimicatechnoacta.ru/article/view/7746/5585; https://chimicatechnoacta.ru/article/downloadSuppFile/7746/1724; https://chimicatechnoacta.ru/article/view/7746
DOI: 10.15826/chimtech.2024.11.3.03
Availability: https://chimicatechnoacta.ru/article/view/7746; https://doi.org/10.15826/chimtech.2024.11.3.03
Rights: (c) 2024 Ravina Meena, Harshita Sachdeva ; http://creativecommons.org/licenses/by/4.0
Accession Number: edsbas.732BA260
Database: BASE