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Alkaloid Profiling as an Approach to Differentiate Lupinus garfieldensis, Lupinus sabinianusand Lupinus sericeus

Title: Alkaloid Profiling as an Approach to Differentiate Lupinus garfieldensis, Lupinus sabinianusand Lupinus sericeus
Authors: Cook, Daniel; Lee, Stephen T.; Pfister, James A.; Stonecipher, Clint A.; Welch, Kevin D.; Green, Benedict T.; Panter, Kip E.
Source: Phytochemical Analysis ; volume 23, issue 3, page 278-284 ; ISSN 0958-0344 1099-1565
Publisher Information: Wiley
Publication Year: 2011
Collection: Wiley Online Library (Open Access Articles via Crossref)
Description: Introduction Many species in the Lupinus genus are poorly defined morphologically, potentially resulting in improper taxonomic identification. Lupine species may contain quinolizidine and/or piperidine alkaloids that can be acutely toxic and/or teratogenic, the latter resulting in crooked calf disease. Objective To identify characteristic alkaloid profiles of Lupinus sabinianus , L. garfieldensis and L. sericeus which would aid in discriminating these species from each other and from L. sulphureus . Methods and materials Quinolizidine and piperidine alkaloids were extracted from herbarium specimens and recent field collections of L. sabinianus , L. garfieldensis and L. sericeus . The alkaloid composition of each species was defined using GC‐FID and GC‐MS and compared using multivariate statistics. Results Each of the three species investigated contained a diagnostic chemical fingerprint composed of quinolizidine and/or piperidine alkaloids. Conclusion The alkaloid profiles of Lupinus sabinianus , L. garfieldensis and L . sericeus can be used as a tool to discriminate these species from each other and L. sulphureus as long as one considers locality of the collection in the case of L. sabinianus . Published 2011. This article is a US Government work and is in the public domain in the USA.
Document Type: article in journal/newspaper
Language: English
DOI: 10.1002/pca.1355
DOI: 10.1002/pca.1355/fullpdf
Availability: http://dx.doi.org/10.1002/pca.1355; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpca.1355; http://onlinelibrary.wiley.com/wol1/doi/10.1002/pca.1355/fullpdf
Rights: http://onlinelibrary.wiley.com/termsAndConditions#vor
Accession Number: edsbas.7FC464D1
Database: BASE