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Effect of High-Temperature Isothermal Annealing on the Structure and Properties of Multicomponent Compact Ti-Al(Nb,Mo,B)-Based Materials Fabricated via Free SHS-Compression

Title: Effect of High-Temperature Isothermal Annealing on the Structure and Properties of Multicomponent Compact Ti-Al(Nb,Mo,B)-Based Materials Fabricated via Free SHS-Compression
Authors: Pavel Bazhin; Ivan Nazarko; Arina Bazhina; Andrey Chizhikov; Alexander Konstantinov; Artem Ivanov; Mikhail Antipov; Pavel Stolin; Svetlana Agasieva; Varvara Avdeeva
Source: Metals ; Volume 15 ; Issue 10 ; Pages: 1088
Publisher Information: Multidisciplinary Digital Publishing Institute
Publication Year: 2025
Collection: MDPI Open Access Publishing
Subject Terms: intermetallic compound; combustion; compression; shear deformation; annealing
Description: This study investigates TNM-type titanium aluminide alloys, representing the third generation of β-stabilized γ-TiAl heat-resistant materials. The aim of this work is to study the combustion characteristics and to produce compact materials via the free SHS compaction method from initial powder reagents taken in the following ratio (wt%): 51.85Ti–43Al–4Nb–1Mo–0.15B, as well as to determine the effect of high-temperature isothermal annealing at 1000 °C on the structure and properties of the obtained materials. Using free SHS compression (self-propagating high-temperature synthesis), we synthesized compact materials from a 51.85Ti–43Al–4Nb–1Mo–0.15B (wt%) powder blend. Key combustion parameters were optimized to maximize the synthesis temperature, employing a chemical ignition system. The as-fabricated materials exhibit a layered macrostructure with wavy interfaces, aligned parallel to material flow during compression. Post-synthesis isothermal annealing at 1000 °C for 3 h promoted further phase transformations, enhancing mechanical properties including microhardness (up to 7.4 GPa), Young’s modulus (up to 200 GPa) and elastic recovery (up to 31.8%). X-ray powder diffraction, SEM, and EDS analyses confirmed solid-state diffusion as the primary mechanism for element interaction during synthesis and annealing. The developed materials show promise as PVD targets for depositing heat-resistant coatings.
Document Type: text
File Description: application/pdf
Language: English
Relation: https://dx.doi.org/10.3390/met15101088
DOI: 10.3390/met15101088
Availability: https://doi.org/10.3390/met15101088
Rights: https://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.A4EC99C7
Database: BASE