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Long-term aging of SiO 2 /HfO 2 PIAD-deposited Laser Mégajoule polarizer coatings

Title: Long-term aging of SiO 2 /HfO 2 PIAD-deposited Laser Mégajoule polarizer coatings
Authors: Soutenain, Arthur; Chorel, Marine; Lavastre, Eric; Guy, Mathilde; Laborde, Etienne; Cornette, Julie; Carles, Pierre; Yvernaud, Eloïse; Launay, Yann; Colas, Maggy; Mireles, Marcela; Rigatti, Amy; Ducros, Cedric; Dublanche-Tixier, Christelle
Contributors: Institut de Recherche sur les CERamiques (IRCER); Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut Matériaux Procédés Environnement Ouvrages (IMPEO); Université de Limoges (UNILIM)-Université de Limoges (UNILIM); Centre d'études scientifiques et techniques d'Aquitaine (CESTA-CEA) (CESTA); Direction des Applications Militaires (DAM); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA); Interactions, transferts, ruptures artistiques et culturelles (InTRu); Université de Tours (UT); IRCER - Axe 3 : organisation structurale multiéchelle des matériaux (IRCER-AXE3); Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut Matériaux Procédés Environnement Ouvrages (IMPEO); University of Rochester USA; ARC-Nucleart CEA Grenoble (NUCLEART); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Ville de Grenoble-Ministère de la Culture (MC); IRCER - Axe 2 : procédés plasmas et lasers (IRCER-AXE2)
Source: ISSN: 1094-4087 ; Optics Express ; https://unilim.hal.science/hal-05491593 ; Optics Express, 2025, 33 (20), pp.43116. ⟨10.1364/OE.564390⟩.
Publisher Information: CCSD; Optical Society of America - OSA Publishing
Publication Year: 2025
Collection: Université François-Rabelais de Tours: HAL
Subject Terms: [CHIM]Chemical Sciences
Description: International audience ; The 176 beams of the Laser Mégajoule (LMJ) are equipped with meter-scale polarizers that filter parasitic light generated before amplification. These multilayer dielectric coatings present instabilities over the years that can lead to a significant transmission loss. To evaluate the causes, HfO 2 and SiO 2 coatings were deposited by evaporation with and without plasma-assistance. Our studies show that a spectral redshift of the polarizers over the years is mainly generated by the SiO 2 layers. A correlation between aging and coatings' moisture sensitivity is evidenced and interpreted as a consequence of water diffusion and the hydrolysis of SiO 2 . Hydrothermal treatments successfully accelerated aging, offering a promising method to stabilize the coating before use.
Document Type: article in journal/newspaper
Language: English
DOI: 10.1364/OE.564390
Availability: https://unilim.hal.science/hal-05491593; https://doi.org/10.1364/OE.564390
Accession Number: edsbas.A7AED988
Database: BASE