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Kinetic Investigation of Dyeing Polyamide Fabrics with Acid Dyestuff in Microwave and Conventional Heating Media

Title: Kinetic Investigation of Dyeing Polyamide Fabrics with Acid Dyestuff in Microwave and Conventional Heating Media
Authors: Raşit Dağlı; Murat Teker; Ayşe Usluoğlu
Source: Processes ; Volume 14 ; Issue 6 ; Pages: 992
Publisher Information: Multidisciplinary Digital Publishing Institute
Publication Year: 2026
Collection: MDPI Open Access Publishing
Subject Terms: polyamide; microwave; acid dyes; kinetic parameters; Arrhenius constant; activation energy
Subject Geographic: agris
Description: In this study, the dyeing kinetics of polyamide fabrics with acid dyes, such as Telon Blue M2R, under both conventional and microwave-assisted heating conditions were comprehensively investigated. While the conventional dyeing reaction was completed in 30 min, microwave-assisted dyeing was performed in the microwave device for 10 min. Dyeing kinetics were investigated as a function of reaction time, reaction concentration and dyeing temperatures. The K/S values (color depth) of the dyed fabrics were correlated with the concentration. A significant reduction in the dyeing process time for polyamide fabric was observed with microwave heating compared to the conventional method. Kinetic analysis revealed that the Pseudo-Second-Order (PSO) kinetic model provides a better fit to the experimental data on the diffusion process of acid dye in polyamide fabrics, as evidenced by higher correlation coefficients (R2) compared to the Pseudo-First-Order (PFO) model. The activation energy of the reaction in dyeing was found to be 63.27 kJ/mol, and the Arrhenius constant was determined as 7.20 × 1010 L/g·min in conventional media and 18.70 × 1010 L/g·min in microwave media. The Arrhenius factor in the microwave medium was more than two times higher than in the conventional media.
Document Type: text
File Description: application/pdf
Language: English
Relation: Materials Processes; https://dx.doi.org/10.3390/pr14060992
DOI: 10.3390/pr14060992
Availability: https://doi.org/10.3390/pr14060992
Rights: https://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.AB7726E2
Database: BASE