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Microwave assisted cold consolidation of alkali activated suspension of glass waste powders

Title: Microwave assisted cold consolidation of alkali activated suspension of glass waste powders
Authors: Tameni G.; Carollo F.; Cavazzini A. M.; Forzan M.; Bernardo E.
Contributors: Tameni, G.; Carollo, F.; Cavazzini, A. M.; Forzan, M.; Bernardo, E.
Publisher Information: Elsevier B.V.
Publication Year: 2025
Collection: Padua Research Archive (IRIS - Università degli Studi di Padova)
Subject Terms: Alkali activation; Boro-alumino-silicate gla; Microwave assisted process
Description: Boro-alumino-silicate pharmaceutical glass has been considered as feedstock for several alkali activated materials. The present paper is intended to investigate the impact of microwave-assisted process on the hardening phase of alkali-activated materials, beyond the use of fine glass powders suspended in mild alkaline solution (2.5 M, KOH) and dried at only 40 °C. The results indicate a significant reduction in curing time, with interesting consequences on the hardening mechanism. Stable compacts are achieved through bridging of adjacent particles, in turn determined by condensation reactions at the surface hydrated layers, upon drying. Drying under microwave heating promotes the chemical stability of a gel phase, formed by reaction of glass components released in the activating solution. In fact, this process enhances the ‘trapping’ of alkali ions in hydrated carbonates. The application of microwave technology results in a reduction of depolymerization within the gel phase. Furthermore, it is observed that the mechanical compressive strength of the activated materials is notably improved when subjected to microwaved irradiation.
Document Type: article in journal/newspaper
Language: English
Relation: info:eu-repo/semantics/altIdentifier/wos/WOS:001443102000001; volume:389; journal:MATERIALS LETTERS; https://hdl.handle.net/11577/3556849
DOI: 10.1016/j.matlet.2025.138354
Availability: https://hdl.handle.net/11577/3556849; https://doi.org/10.1016/j.matlet.2025.138354
Rights: info:eu-repo/semantics/openAccess ; license:Creative commons ; license uri:http://creativecommons.org/licenses/by/4.0/
Accession Number: edsbas.ADF6D4B8
Database: BASE