| Title: |
Facile Phenylphosphinidene Transfer Reactions from Carbene–Phosphinidene Zinc Complexes |
| Authors: |
Krachko, Tetiana; Bispinghoff, Mark; Tondreau, Aaron M.; Stein, Daniel; Baker, Matthew; Ehlers, Andreas W.; Slootweg, J. Chris; Grützmacher, Hansjörg |
| Contributors: |
FP7 People: Marie-Curie Actions |
| Source: |
Angewandte Chemie International Edition ; volume 56, issue 27, page 7948-7951 ; ISSN 1433-7851 1521-3773 |
| Publisher Information: |
Wiley |
| Publication Year: |
2017 |
| Collection: |
Wiley Online Library (Open Access Articles via Crossref) |
| Description: |
Phosphinidenes [R‐P] are convenient P 1 building blocks for the synthesis of a plethora of organophosphorus compounds. Thus far, transition‐metal‐complexed phosphinidenes have been used for their singlet ground‐state reactivity to promote selective addition and insertion reactions. One disadvantage of this approach is that after transfer of the P 1 moiety to the substrate, a challenging demetallation step is required to provide the free phosphine. We report a simple method that enables the Lewis acid promoted transfer of phenylphosphinidene, [PhP], from NHC=PPh adducts (NHC=N‐heterocyclic carbene) to various substrates to produce directly uncoordinated phosphorus heterocycles that are difficult to obtain otherwise. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1002/anie.201703672 |
| Availability: |
https://doi.org/10.1002/anie.201703672; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201703672; https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201703672 |
| Rights: |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
| Accession Number: |
edsbas.B2E3E8B2 |
| Database: |
BASE |