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The spectrum of ammonia near 0.793 μm

Title: The spectrum of ammonia near 0.793 μm
Authors: Zobov, NF; Bertin, T; Vander Auwera, J; Civiš, S; Knížek, A; Ferus, M; Ovsyannikov, RI; Makhnev, VY; Tennyson, J; Polyansky, OL
Source: Journal of Quantitative Spectroscopy and Radiative Transfer , 273 , Article 107838. (2021)
Publication Year: 2021
Collection: University College London: UCL Discovery
Description: Two sets of NH3 absorption spectra covering the 0.793 μm region are recorded using two Bruker IFS 125 HR Fourier transform spectrometers. Three unapodized absorption spectra are recorded in Brussels over the range 11000−14500 cm−1 and the positions and intensities of 1114 ammonia lines observed in the 12491−12810 cm−1 region are measured using a multi-spectrum least squares fitting algorithm. 367 additional lines are identified in an ammonia absorption spectrum recorded in two steps at the J. Heyrovsky Institute of Physical Chemistry in Prague, using two different interference filters covering the 12000−12500 and 12400−13000 cm−1 ranges. The 1481 measured ammonia lines are analyzed using an empirical line list computed using variational nuclear motion calculations and ground state combination differences. Transitions are assigned to vibrational states with 4νNH stretching excitation (v1+v3=4). 278 out of the 1481 measured lines are assigned to 300 transitions and 119 upper state energy levels are derived from the frequencies of the assigned transitions.
Document Type: article in journal/newspaper
File Description: text
Language: English
Relation: https://discovery.ucl.ac.uk/id/eprint/10133058/
Availability: https://discovery.ucl.ac.uk/id/eprint/10133058/1/1-s2.0-S0022407321003319-main.pdf; https://discovery.ucl.ac.uk/id/eprint/10133058/
Rights: open
Accession Number: edsbas.B338CD47
Database: BASE