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Exomol Molecular Line Lists XXX: a Complete High-accuracy Line List for Water

Title: Exomol Molecular Line Lists XXX: a Complete High-accuracy Line List for Water
Authors: Polyansky, OL; Kyuberis, AA; Zobov, NF; Tennyson, J; Yurchenko, SN; Lodi, L
Source: Monthly Notices of the Royal Astronomical Society , 480 (2) pp. 2597-2608. (2018)
Publication Year: 2018
Collection: University College London: UCL Discovery
Subject Terms: molecular data; opacity; planets and satellites: atmospheres; stars: atmospheres; stars: low-mass; stars: brown dwarfs. astronomical data bases: miscellaneous
Description: A new line list for H216O is presented. This line list, which is called POKAZATEL, includes transitions between rotational-vibrational energy levels up to 41 000 cm-1and is the most complete to date. The potential energy surface (PES) used for producing the line list was obtained by fitting a high-quality ab initio PES to experimental energy levels with energies of 41 000 cm-1and for rotational excitations up to J = 5. The final line list comprises all energy levels up to 41 000 cm-1and rotational angular momentum J up to 72. An accurate ab initio dipole moment surface was used for the calculation of line intensities and reproduces high-precision experimental intensity data with an accuracy close to 1 per cent. The final line list uses empirical energy levels, whenever they are available, to ensure that line positions are reproduced as accurately as possible. The POKAZATEL line list contains over 5 billion transitions and is available from the ExoMol website (www.exomol.com) and the CDS data base.
Document Type: article in journal/newspaper
File Description: text
Language: English
Relation: https://discovery.ucl.ac.uk/id/eprint/10059787/1/sty1877.pdf; https://discovery.ucl.ac.uk/id/eprint/10059787/
Availability: https://discovery.ucl.ac.uk/id/eprint/10059787/1/sty1877.pdf; https://discovery.ucl.ac.uk/id/eprint/10059787/
Rights: open
Accession Number: edsbas.B8C77E7F
Database: BASE