| Title: |
Complexation to [Ru(bpy)$_2$]$^{2+}$: the trick to functionalize 3,3′-disubstituted-2,2′-bipyridine |
| Authors: |
Guillo, Pascal; Hamelin, Olivier; Pécaut, Jacques; Ménage, Stéphane |
| Contributors: |
Laboratoire de Chimie et Biologie des Métaux (LCBM - UMR 5249); Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Institut de Recherche Interdisciplinaire de Grenoble (IRIG); Direction de Recherche Fondamentale (CEA) (DRF (CEA)); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA); Laboratoire de Reconnaissance Ionique et Chimie de Coordination (UMR E-3 CEA/UJF); Laboratoire de Reconnaissance Ionique et Chimie de Coordination; Service de Chimie Inorganique et Biologique (SCIB - UMR E3); Institut Nanosciences et Cryogénie (INAC); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Centre National de la Recherche Scientifique (CNRS) |
| Source: |
ISSN: 0040-4039. |
| Publisher Information: |
CCSD; Elsevier |
| Publication Year: |
2013 |
| Collection: |
Université Grenoble Alpes: HAL |
| Subject Terms: |
3-3′-Disubstituted-2-2′-bipyridine; Ruthenium complexes; Metalloligands; [CHIM.ORGA]Chemical Sciences/Organic chemistry |
| Description: |
International audience ; While many papers reported the synthesis and chemical transformations of x,x′-disubstituted-2,2′-bipyridine with x = 4, 5 or 6, this is not the case when x = 3. Though, such 3,3′-disubstituted-2,2′-bipyridines would be a useful building block for the design of new original complexes. Here we report the results of our investigation concerning the synthesis of members of this family. This study led to the formation of several [(2,2′-bipyridine)$_2$Ru(3,3′-dialkylated-2,2′-bipyridine)]$^{2+}$ complexes highlighting a surprising chemical behaviour of the 3,3′-disubstituted-2,2′-bipyridine ligand compared to its 4,4′, 5,5′ and 6,6′-homologues. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| ISBN: |
978-0-04-040391-7; 0-04-040391-2 |
| DOI: |
10.1016/j.tetlet.2012.11.089 |
| Availability: |
https://hal.science/hal-01101300; https://hal.science/hal-01101300v1/document; https://hal.science/hal-01101300v1/file/Guillo2013.pdf; https://doi.org/10.1016/j.tetlet.2012.11.089 |
| Rights: |
info:eu-repo/semantics/OpenAccess |
| Accession Number: |
edsbas.C0D6A932 |
| Database: |
BASE |