| Title: |
Bis[cyclic (alkyl)(amino)carbene] isomers: Stable trans-bis(CAAC) versus facile olefin formation for cis-bis(CAAC) |
| Authors: |
Puerta Lombardi, Braulio M.; Pezoulas, Ethan R.; Suvinen, Roope A.; Harrison, Alexander; Dubrawski, Zachary S.; Gelfand, Benjamin S.; Tuononen, Heikki M.; Roesler, Roland |
| Contributors: |
Horizon 2020 Framework Programme; Natural Sciences and Engineering Research Council of Canada; Canada First Research Excellence Fund |
| Source: |
Chemical Communications ; volume 58, issue 45, page 6482-6485 ; ISSN 1359-7345 1364-548X |
| Publisher Information: |
Royal Society of Chemistry (RSC) |
| Publication Year: |
2022 |
| Description: |
A trans -bis(CAAC) was isolated and shown to be a ditopic ligand for rhodium and iridium. The cis- isomer is unstable towards intramolecular CC-bond formation, however, its formal insertion products into the bonds of H 2 O and NH 3 were identified. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1039/d2cc01476a |
| Availability: |
https://doi.org/10.1039/d2cc01476a; http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01476A |
| Rights: |
http://creativecommons.org/licenses/by-nc/3.0/ |
| Accession Number: |
edsbas.C4662CA8 |
| Database: |
BASE |