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Large-scale High-throughput Screening Revealed 5'-(carbonylamino)-2,3'- bithiophene-4'-carboxylate as Novel Template for Antibacterial Agents

Title: Large-scale High-throughput Screening Revealed 5'-(carbonylamino)-2,3'- bithiophene-4'-carboxylate as Novel Template for Antibacterial Agents
Authors: Ivanenkov, Yan A.; Yamidanov, Renat S.; Osterman, Ilya A.; Sergiev, Petr V.; Aladinskiy, Vladimir A.; Aladinskaya, Anastasia V.; Terentiev, Victor A.; Veselov, Mark S.; Ayginin, Andrey A.; Skvortsov, Dmitry A.; Komarova, Katerina S.; Zagribelnyy, Bogdan A.; Baimiev, Alexey Kh.; Shvetc, Kseniya Yu.; Baimiev, Andrey Kh.; Sofronova, Alina A.; Machulkin, Alexey E.; Petrov, Rostislav A.; Zainullina, Liana F.; Maximova, Marina A.; Zileeva, Zulfiya R.; Vakhitova, Yulia V.; Bezrukov, Dmitry S.; Puchinina, Maria M.; Dontsova, Olga A.
Contributors: Russian Science Foundation; Ministry of Education and Science of the Russian Federation
Source: Current Drug Discovery Technologies ; volume 17, issue 5, page 716-724 ; ISSN 1570-1638
Publisher Information: Bentham Science Publishers Ltd.
Publication Year: 2020
Description: Background: The key issue in the development of novel antimicrobials is a rapid expansion of new bacterial strains resistant to current antibiotics. Indeed, World Health Organization has reported that bacteria commonly causing infections in hospitals and in the community, e.g. E. Coli, K. pneumoniae and S. aureus, have high resistance vs the last generations of cephalosporins, carbapenems and fluoroquinolones. During the past decades, only few successful efforts to develop and launch new antibacterial medications have been performed. This study aims to identify new class of antibacterial agents using novel high-throughput screening technique. Methods: We have designed library containing 125K compounds not similar in structure (Tanimoto coeff.< 0.7) to that published previously as antibiotics. The HTS platform based on double reporter system pDualrep2 was used to distinguish between molecules able to block translational machinery or induce SOS-response in a model E. coli system. MICs for most active chemicals in LB and M9 medium were determined using broth microdilution assay. Results: In an attempt to discover novel classes of antibacterials, we performed HTS of a large-scale small molecule library using our unique screening platform. This approach permitted us to quickly and robustly evaluate a lot of compounds as well as to determine the mechanism of action in the case of compounds being either translational machinery inhibitors or DNA-damaging agents/replication blockers. HTS has resulted in several new structural classes of molecules exhibiting an attractive antibacterial activity. Herein, we report as promising antibacterials. Two most active compounds from this series showed MIC value of 1.2 (5) and 1.8 μg/mL (6) and good selectivity index. Compound 6 caused RFP induction and low SOS response. In vitro luciferase assay has revealed that it is able to slightly inhibit protein biosynthesis. Compound 5 was tested on several archival strains and exhibited slight activity against gram-negative bacteria and ...
Document Type: article in journal/newspaper
Language: English
DOI: 10.2174/1570163816666190603095521
Availability: https://doi.org/10.2174/1570163816666190603095521; https://eurekaselect.com/article/download/172406; https://www.eurekaselect.com/172406/article
Accession Number: edsbas.C9928682
Database: BASE