Selective Mono- and Diamination of 2,6-Dibromopyridine for the Synthesis of Diaminated Proligands
| Title: | Selective Mono- and Diamination of 2,6-Dibromopyridine for the Synthesis of Diaminated Proligands |
|---|---|
| Authors: | Alexander S. Underwood; Mark A. Botrous; Nate T. Lobb; Emmett M. Neal; Charlotte A. Richter; Mathieu A. Sleiman; Adrian B. Frye; Matthew Roberts; Clifford W. Padgett; Gary L. Guillet |
| Publication Year: | 1753 |
| Collection: | University of Sussex (US): Figshare |
| Subject Terms: | Biochemistry; Cell Biology; Molecular Biology; Biotechnology; Ecology; Space Science; Environmental Sciences not elsewhere classified; Biological Sciences not elsewhere classified; Chemical Sciences not elsewhere classified; 3 |
| Description: | Selective mono- or diaminations of 2,6-dibromopyridine were performed using microwave irradiation with water as solvent in 2–2.5 h. The only significant difference between the syntheses was the inclusion of K 2 CO 3 as base and CuI/DMPAO catalyst for the diaminations. The mono- and diaminations had approximately 7 and 2 g isolated yields, respectively. The monoaminated bromopyridines were attached to a TREN scaffolding molecule yielding novel ligands to support extended metal atom chain complexes. |
| Document Type: | article in journal/newspaper |
| Language: | unknown |
| DOI: | 10.1021/acsomega.5c04396.s001 |
| Availability: | https://doi.org/10.1021/acsomega.5c04396.s001; https://figshare.com/articles/journal_contribution/Selective_Mono-_and_Diamination_of_2_6-Dibromopyridine_for_the_Synthesis_of_Diaminated_Proligands/29878756 |
| Rights: | CC BY-NC 4.0 |
| Accession Number: | edsbas.CC692E28 |
| Database: | BASE |