| Title: |
Structure and rearrangement reactions of bis(organosilyl) (organostannyl)hydroxylamines: A joint theoretical/experimental study |
| Authors: |
Schmatz, S.; Ebker, C.; Labahn, T.; Stoll, Hermann; Klingebiel, Uwe |
| Contributors: |
Schmatz, S.; Ebker, C.; Labahn, T.; Stoll, Hermann; Klingebiel, Uwe |
| Publisher Information: |
Amer Chemical Soc |
| Publication Year: |
2003 |
| Collection: |
Georg-August-Universität Göttingen: GoeScholar |
| Description: |
O-Lithium-N,N-bis(tent-butyldimethylsilyl)hydroxylamide reacts with chlorotrimethyl-stannane to give N,O-bis(tert-butyldimethylsilyl)-N-(trimethylstannyl)hydroxylamine (1), the crystal structure of which is presented. The primarily formed N,N-bis(tert-butyldimethylsilyl)O-(trimethylstannyl)hydroxylamine undergoes a dyotropic rearrangement. This reaction mechanism is corroborated by quantum-chemical calculations (B3LYP), partly employing an effective core potential for tin. The possibility for insertion of a stannyl group has been studied by quantum-chemical calculations. The transition states in the various rearrangement reactions of the bis(organylsilyl)stannylhydroxylamine system are discussed in detail. |
| Document Type: |
article in journal/newspaper |
| Language: |
unknown |
| ISBN: |
978-0-00-180689-4; 0-00-180689-0 |
| Relation: |
000180689000017 |
| DOI: |
10.1021/om0206195 |
| Availability: |
https://resolver.sub.uni-goettingen.de/purl?gro-2/46438; https://doi.org/10.1021/om0206195 |
| Rights: |
info:eu-repo/semantics/openAccess |
| Accession Number: |
edsbas.CC9F7F61 |
| Database: |
BASE |