| Title: |
Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals. |
| Authors: |
Butler, MJ; Crimmin, MR |
| Contributors: |
The Royal Society; Engineering & Physical Science Research Council (EPSRC) |
| Source: |
1365 ; 1348 |
| Publisher Information: |
Royal Society of Chemistry |
| Publication Year: |
2016 |
| Collection: |
Imperial College London: Spiral |
| Subject Terms: |
Organic Chemistry; 03 Chemical Sciences |
| Subject Geographic: |
England |
| Description: |
The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| Relation: |
Chemical Communications; http://hdl.handle.net/10044/1/43712; https://dx.doi.org/10.1039/c6cc05702k; UF090149; EP/L011514/1 |
| DOI: |
10.1039/c6cc05702k |
| Availability: |
http://hdl.handle.net/10044/1/43712; https://doi.org/10.1039/c6cc05702k |
| Rights: |
© 2017 The Royal Society of Chemistry. |
| Accession Number: |
edsbas.CFF09B0 |
| Database: |
BASE |