| Title: |
A zirconium squarate metal-organic framework with modulator-dependent molecular sieving properties |
| Authors: |
Bueken, Bart; Reinsch, Helge; Reimer, Nele; Stassen, Ivo; Vermoortele, Frederik; Ameloot, Rob; Stock, Norbert; Kirschhock, Christine; De Vos, Dirk |
| Source: |
ISSN:1359-7345 ; ISSN:1364-548X ; Chemical Communications, vol. 50 (70), (10055-10058. |
| Publisher Information: |
Royal Society of Chemistry |
| Publication Year: |
2014 |
| Subject Terms: |
Science & Technology; Physical Sciences; Chemistry; Multidisciplinary; HYDROTHERMAL SYNTHESIS; TRANSITION; SERIES; TOOL; 03 Chemical Sciences; Organic Chemistry; 34 Chemical sciences; 40 Engineering |
| Description: |
We report the first zirconium metal-organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis. ; sponsorship: BB, IS and DDV acknowledge the FWO Flanders for financial support. NR and NS are thankful for the support of the DFG (SPP1362). The authors would like to thank K. Duerinckx for NMR measurements and P. Valvekens for N2 sorption. ; status: Published |
| Document Type: |
article in journal/newspaper |
| File Description: |
application/pdf |
| Language: |
English |
| Relation: |
https://lirias.kuleuven.be/handle/123456789/469655; https://doi.org/10.1039/C4CC03764B; https://pubmed.ncbi.nlm.nih.gov/25036867 |
| DOI: |
10.1039/C4CC03764B |
| Availability: |
https://lirias.kuleuven.be/handle/123456789/469655; https://lirias.kuleuven.be/retrieve/c9514a2d-e9a6-4640-9a3e-5b45baf7dd83; https://doi.org/10.1039/C4CC03764B; https://pubmed.ncbi.nlm.nih.gov/25036867 |
| Rights: |
info:eu-repo/semantics/openAccess ; public |
| Accession Number: |
edsbas.D3FBC335 |
| Database: |
BASE |