| Title: |
Synthesis, structure and magnetic properties of a series of Ln( iii ) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization |
| Authors: |
Long, Jérôme; Skvortsov, Grigorii; Cherkasov, Anton; Lyssenko, Konstantin, A.; Poddel'Sky, Andrei; Guari, Yannick; Larionova, Joulia; Trifonov, Alexander, A. |
| Contributors: |
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM); Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS); G. A. Razuvaev Institute of Organometallic Chemistry; Russian Academy of Sciences Moscow (RAS); A. N. Nesmeyanov Institute of Organoelement Compounds (INEOS) |
| Source: |
ISSN: 1477-9226. |
| Publisher Information: |
CCSD; Royal Society of Chemistry |
| Publication Year: |
2019 |
| Collection: |
Université de Montpellier: HAL |
| Subject Terms: |
[CHIM.COOR]Chemical Sciences/Coordination chemistry |
| Description: |
International audience ; We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1039/C9DT00738E |
| Availability: |
https://hal.science/hal-02270823; https://hal.science/hal-02270823v1/document; https://hal.science/hal-02270823v1/file/preprint.pdf; https://doi.org/10.1039/C9DT00738E |
| Rights: |
info:eu-repo/semantics/OpenAccess |
| Accession Number: |
edsbas.D46170D1 |
| Database: |
BASE |