| Title: |
The Impact of Carbon Nanotube Length and Diameter on their Global Alignment by Dead‐End Filtration |
| Authors: |
Rust, Christian; Shapturenka, Pavel; Spari, Manuel; Jin, Qihao; Li, Han; Bacher, Andreas; Guttmann, Markus; Zheng, Ming; Adel, Tehseen; Walker, Angela R. Hight; Fagan, Jeffrey A.; Flavel, Benjamin S. |
| Source: |
Small ; volume 19, issue 10 ; ISSN 1613-6810 1613-6829 |
| Publisher Information: |
Wiley |
| Publication Year: |
2022 |
| Collection: |
Wiley Online Library (Open Access Articles via Crossref) |
| Description: |
Dead‐end filtration has proven to effectively prepare macroscopically (3.8 cm 2 ) aligned thin films from solutionbased single‐wall carbon nanotubes (SWCNTs). However, to make this technique broadly applicable, the role of SWCNT length and diameter must be understood. To date, most groups report the alignment of unsorted, large diameter (≈1.4 nm) SWCNTs, but systematic studies on their small diameter are rare (≈0.78 nm). In this work, films with an area of A = 3.81 cm 2 and a thickness of ≈40 nm are prepared from length‐sorted fractions comprising of small and large diameter SWCNTs, respectively. The alignment is characterized by cross‐polarized microscopy, scanning electron microscopy, absorption and Raman spectroscopy. For the longest fractions ( L avg = 952 nm ± 431 nm, Δ = 1.58 and L avg = 667 nm ± 246 nm, Δ = 1.55), the 2D order parameter, S2D, values of ≈0.6 and ≈0.76 are reported for the small and large diameter SWCNTs over an area of A = 625 µm 2 , respectively. A comparison of Derjaguin, Landau, Verwey, and Overbeek (DLVO) theory calculations with the aligned domain size is then used to propose a law identifying the required length of a carbon nanotube with a given diameter and zeta potential. |
| Document Type: |
article in journal/newspaper |
| Language: |
English |
| DOI: |
10.1002/smll.202206774 |
| Availability: |
https://doi.org/10.1002/smll.202206774; https://onlinelibrary.wiley.com/doi/pdf/10.1002/smll.202206774; https://onlinelibrary.wiley.com/doi/full-xml/10.1002/smll.202206774 |
| Rights: |
http://creativecommons.org/licenses/by/4.0/ |
| Accession Number: |
edsbas.D5418136 |
| Database: |
BASE |